ISSN 0021-3640, JETP Letters, 2014, Vol. 99, No. 1, pp. 32–36. © Pleiades Publishing, Inc., 2014.
Original Russian Text © V.B. Efimov, A.V. Lokhov, L.P. Mezhov-Deglin, C. Dewhurst, V.V. Nesvizhevsky, G.V. Kolmakov, 2014, published in Pis’ma v Zhurnal Eksperimental’noi
i Teoreticheskoi Fiziki, 2014, Vol. 99, No. 1, pp. 35–39.
32
1. INTRODUCTION
When the flux of gaseous
4
He, which contains ≤2%
of the impurity of vapors of atomic or molecular gases
or vapors of a liquid under normal conditions inside
the working cell filled with He-II, is condensed on the
surface of superfluid He-II cooled below 1.8 K, a
porous impurity–helium condensate impregnated by
the superfluid liquid—impurity gel—is formed [1–3].
The studies of the structure and properties of impu-
rity-gel samples that are formed when various impuri-
ties are introduced in He-II were reviewed in [4–6].
It was found that the dispersive system (backbone)
of an as-prepared impurity gel sample is formed by
aggregates consisting of impurity nanoclusters, more
precisely, of impurity van der Waals complexes, which
appear in dense helium vapor at the vapor–superfluid
liquid interface and consist of impurity nanoclusters
coated with one or two layers of atoms of solid
4
He.
The helium layer prevents the coalescence and col-
lapse of impurity clusters. Liquid helium filling pores
between impurity aggregates serves as a dispersive
medium of the sample formed in He-II. It is notewor-
thy that the properties of liquid helium in restricted
geometry, in particular, the transition temperature of
the liquid in nanopores to the superfluid state, can sig-
nificantly differ from the properties of the bulk liquid
[7]. This can be a reason for the appearance of thermal
instability in the bulk of helium: an irreversible
increase in the absorption of ultrasound, rise of lumi-
nescence in the condensate containing nitrogen atoms
in the molecular matrix of nitrogen helium [1, 4, 6],
and a growth of the content of small clusters in deute-
rium gel [5, 8] at temperatures T ≈ 2.0 K noticeably
below the transition point of the liquid surrounding
the sample from the superfluid to normal state (T
λ
=
2.172 K). Savich and Shalnikov [9] long ago observed
the thermal instability of the hydrogen-condensate
layer that was formed on the surface of He-II at the
introduction of the gaseous hydrogen impurity into
the cryostat (solid hydrogen is lighter than liquid
helium) and “exploded with the formation of a halo of
hydrogen particles” at the heating of the liquid and
transition from He-II to He-I.
Thus, impurity gels constitute a new class of non-
crystalline materials (quantum soft matter), which are
formed in a quantum liquid at low temperatures owing
to the relatively weak van der Waals interaction of neu-
tral impurity nanoclusters between each other and
with the surrounding superfluid liquid. These gels can
be applied in modern science and technologies, e.g.,
in the development of new power-consuming low-
temperature materials with a high content of free rad-
icals (in the simplest case, atoms of molecular materi-
als) in a molecular matrix [1, 2, 4, 6], and in the study
of the features of chemical reactions and phenomena
on the surface of nanocrystalline catalysts at low and
ultralow temperatures. Nanocluster gels of materials
weakly absorbing neutrons, primarily, gels of heavy
water and deuterium, can be used as moderators of
cold neutrons [5, 10–14]. Coatings made of nanopo-
wders that appear at the decay of such gels [15, 16] can
be used in neutron guides as reflectors of cold and
ultracold neutrons [17–21].
The interaction of cold neutrons with nanocluster
oxygen gel has not yet been studied. Our study was
Nanocluster Magnetic Gel in Superfluid He-II
V. B. Efimov
a
, A. V. Lokhov
a
, L. P. Mezhov-Deglin
a
, C. Dewhurst
b
,
V. V. Nesvizhevsky
b
, and G. V. Kolmakov
c
a
Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow region, 142432 Russia
e-mail: mezhov@issp.ac.ru
b
Institut Laue-Langevin, Grenoble 38000, France
c
New York City College of Technology, City University of New York, Brooklyn, 11201 NY, USA
Received December 11, 2013
The first results of the study of the structure of an impurity oxygen gel in superfluid He-II and in normal liquid
helium have been obtained by the small-angle neutron scattering (SANS) method with cold neutrons. The
angular dependence of the neutron scattering intensity I(q) indicates that the characteristic sizes of nanoclus-
ter aggregates forming a dispersive system (backbone) of an oxygen gel sample are distributed from 1 to
≈100 nm. According to the estimates made, if the working cell with superfluid helium cooled below 1.8 K is
placed in a magnetic field of H ≥ 200 G, the magnetic structure of the nanocluster sample of oxygen gel,
which is formed at the condensation of the flow of gaseous
4
He with the impurity of O
2
vapor on the surface
of He-II, will be close to ferromagnetic.
DOI: 10.1134/S0021364014010044