*Corresponding Author E-mail: hemantdrd@hotmail.com
© 2002 Association of Applied Biologists
Ann. appl. Biol. (2002), 140:159-162
Printed in Great Britain 159
Isolation of bacterial consortia for degradation of p-nitrophenol from
agricultural soil
By ASIFA A QURESHI and HEMANT J PUROHIT*
National Environmental Engineering Research Institute, Nehru Marg, Nagpur 4400 20, India
(Accepted 7 December 2001; Received 16 May 2001)
Summary
A bacterial consortium has been isolated containing Pseudomonas spp. strains S1 and S2, which was
able to degrade p-nitrophenol (PNP). The strains were isolated from agricultural soil contaminated
with organophosphorus pesticides. Pseudomonas spp. strain S2 could convert p-nitrophenol to 4-
nitrocatechol (4NC) after pre-exposure to phenol, when PNP was used as the only carbon source in the
medium. Pseudomonas spp. strain S2, when mixed with strain S1 in the ratio 1:5 respectively,
decolorised PNP completely.
Key words: p-nitrophenol, 4-nitrocatechol, phenol, Pseudomonas spp.
Introduction
We are working on developing a culture collection
from the environmental niches contaminated with
phenolic and substituted phenolic waste. We have
isolated cultures for treatment of PNP (Qureshi et
al., 2001), chlorophenols (Atuanya et al., 2000),
aminophenols (Kutty et al., 2000) and are developing
strategies to track phenols in the environment
(Kapley & Purohit, 2000).
We have reported degradation of p-nitrophenol
(PNP) using Pseudomonas SF1, isolated from an
industrial dumpsite (Qureshi et al., 2001). The strain
utilises PNP, via the intermediate 1,4-benzoquinone,
as also reported by other groups (Spain, 1995; Zeyer
& Kocher, 1988). The present study reports
degradation of PNP with two different soil isolates
in co-culture (S1 and S2) from agricultural land
contaminated with organophosphorus pesticides.
Pseudomonas strain S2 converted PNP to 4-
nitrocatechol (4NC); followed by further degradation
by Pseudomonas strain S1. Furthermore, it has been
demonstrated that a minimal ratio of the two cultures
is required for PNP utilisation.
Experimental Procedures
Media and culture conditions
The mineral medium had the following
composition: 36.9 mM Na
2
HPO
4
, 20.3 mM KH
2
PO
4
,
4.67 mM NH
4
Cl, 0.68 mM CaCl
2
, 0.811 mM MgSO
4
,
0.0035 mM FeSO
4
; and was used for both the
enrichment and growth studies. The carbon source
used in the cultivation medium was phenol (1 mM)
or PNP (0.07 mM). The culture temperature was kept
at 30°C with shaking at 150 rpm.
Enrichment and isolation
The enrichment approach was used as described
earlier (Qureshi et al. , 2001). The soil sample
derived from the contaminated agricultural field was
suspended as slurry in Na-K phosphate buffer pH7
and used as an inoculum for the enrichment of
microorganisms. The minimal media amended with
0.07 mM PNP was inoculated with the soil slurry
and incubated for 3 wk in suspension culture in the
shaking incubator with regular spiking with the same
amount of PNP after every 24 h. In a 24 h period,
the yellow coloured growth medium turned
colourless due to PNP utilisation. The sample from
the reactor was diluted and streaked on a minimal
media plate amended with PNP (0.07 mM). After 3
days of incubation, the colonies that showed
colorless zones were picked and tested for their
ability to transform PNP in the liquid cultures.
Apparently, the colony which showed the colourless
zone appeared to be a co-culture when it was
streaked onto an LB plate, with two different colony
morphologies. According to the Bergeys Manual
of Systematic Bacteriology both the strains were
classified and identified as pseudomonads (Palleroni,
1984). Neither culture grown separately could utilise
PNP as sole source of carbon.
Transformation of PNP to 4-nitrocatechol by
Pseudomonas strain S2
Cells were grown in LB medium overnight and
harvested by centrifugation (6000 X g) and were
then washed with phosphate buffer (pH 7). The cell
pellet was resuspended in minimal medium with 1
mM phenol as a sole source of carbon and incubated
for 48 h at 30°C for pre-adaptation. The phenol
grown cells were pelleted and inoculated into the