Research paper
Microstructure and mechanical properties of cementless construction
materials from thermal engineering wastes
Vs
evolod A. Mymrin
a, *
, Marcelo V. da Cunha
b
, Kirill P. Alekseev
a
, Haroldo Ponte
b
,
Rodrigo E. Catai
a
, Cezar A. Romano
a
a
Technological Federal University of Paran a (UTFPR), Curitiba, Brazil
b
Federal University of Paran a (UFPR), Curitiba, Brazil
highlights
New construction material from three types of Porcelain industry wastes.
Lime production waste was used as binder material.
Uniaxial resistance strength at the age of one year reached 14 MPa.
Structure formation processes were determined by XRD, SEM and EDS methods.
Utilization of industrial wastes has high economical and environment efficiency.
article info
Article history:
Received 9 November 2014
Accepted 14 February 2015
Available online 21 February 2015
Keywords:
Ceramics industry
Fired/unfired wastes
Lime production wastes
Structures formation processes
Mechanical properties
Environment protection
abstract
In order to solve environment problems of ceramics industry new compositions of materials were
developed from three types of porcelain production tails e fired wastes (FW), unfired wastes (UW) and
wastewater treatment plant sludge (WTPS) e as the main raw materials of new compositions of
cementless building materials. The binder material used here was lime production waste (LPW), i.e.,
incompletely burned lime. The uniaxial compressive strength of the new materials containing 15 wt% of
LPW at one year of age increased up to 14.2 MPa and the materials with 5% LPW content increased up to
8.6 MPa, exceeding the specifications of Brazilian standards for hollow concrete blocks. The water ab-
sorption (W
A
) coefficient of different compositions at the age of 28 days ranged from 17.9 to 24.6%, but
this does not affect the values of the water resistance coefficient (0.71e0.85). X-ray diffraction and
scanning electron microscopy analyses indicated that the strength of the new materials increases due to
the synthesis of amorphous and crystalline compounds. The feasibility of the new materials based on the
use of four types of industrial wastes for the production of new building materials with high mechanical
properties, which meet the requirements of national standards.
© 2015 Elsevier Ltd. All rights reserved.
1. Introduction
The strategy of companies to improve their environmental
performance is an essential part of their social function, since it not
only satisfies their clients' wishes but also improves their re-
lationships with environmental control agencies and with society
in general. Mere compliance with the minimum standards
established by environmental laws is not considered sufficient to
maintain a competitive advantage, above all in export markets [1].
The need to recycle industrial wastes is increasing apace due to the
rising cost of natural raw materials and effluent disposal, and the
need for compliance with environmental legislation. It is estimated
that 175 million tons of quarrying waste are produced each year [2].
The consumption of only natural decorative stone materials
worldwide is growing annually by 7e9% and now stands at about
700 million m
2
[3]. ANEFA e National Association of Spanish
Manufacturers Association of AggregateseAggregates Producers e
informed [4] that the consumption of natural aggregates in Spain in
2007 reached the 479 million tons in the construction sector and 72
* Corresponding author. Federal Technological University of Parana, str. Deputado
Heitor de Alencar Furtado, 4900, Campus Curitiba, CEP: 81280-340, Ecoville, Par-
an a, Brazil. Tel.: þ55 41 3279 4518.
E-mail address: seva6219@gmail.com (V.A. Mymrin).
Contents lists available at ScienceDirect
Applied Thermal Engineering
journal homepage: www.elsevier.com/locate/apthermeng
http://dx.doi.org/10.1016/j.applthermaleng.2015.02.029
1359-4311/© 2015 Elsevier Ltd. All rights reserved.
Applied Thermal Engineering 81 (2015) 185e192