International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395 -0056
Volume: 02 Issue: 02 | May-2015 www.irjet.net p-ISSN: 2395-0072
© 2015, IRJET.NET- All Rights Reserved Page 1025
Experimental Investigation and Measurement of Contact Angle of Drop
on Surface with Triton X-100 as Surfactant in Pure Water
Sanjay Mane
1
, Ravindra Yadav
2
, K M Jagdale
3
, T S Gulavane
4
1
Student, Mechanical Engineering Department, Dr. JJMCOE, Jaysingpur, Maharashtra, India
2
Professor, Mechanical Engineering Department, Dr. JJMCOE, Jaysingpur, Maharashtra, India
3
Assistant Professor, Mechanical Engineering Department, AITRC, Vita, Maharashtra, India
4
Assistant Professor, Mechanical Engineering Department, AITRC, Vita, Maharashtra, India
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Abstract- Boiling using surfactant is important
in many industrial applications such as the
petrochemical processing, pharmaceutical, refining,
refrigeration, and food processing, among others.
Moreover, surfactants in trace amounts are
present in boilers of conventional power plants.
The experimental set up for the present
investigation includes electric heating wire (D= 0.3
mm and L= 100 mm) submerged in water and
mounted horizontally. Two thermocouples and a
digital indicator measured the temperature of the
heater surface and solution temperature. The actual
heat transfer rate is obtained by multiplying the
voltmeter and ammeter readings. The main heater
also present which heats the solution at 40
0
C to 50
0
C.
The camera was fixed to take photos of water drop on
nichrome wire for measurement of contact angle.
Several different surfactants were
available, to check boiling behavior with and without
surfactant in water. For this test Triton X-100
(Octylphenol Ethoxylate) was used as surfactant in
pure water to reduce the contact angle and increase
the heat transfer coefficient. Pool boiling experiments
were carried out a relatively wide range of surfactant
concentrations Triton X-100 (50 - 200) ppm and heat
fluxes (61.53 - 152.79) kw/m
2
. The boiling results
show that with the addition of small amounts of
surfactants, the saturated nucleate pool boiling heat
transfer coefficient of water is found to be altered due
to reduction in the surface tension and this enhances
the heat transfer. The photographic and visual
observations indicate boiling behavior is different
than pure water with surfactant and shaped bubbles
clustering on the heater surface reducing coalescence.
Key Words: Contact angle, wettability, heat transfer,
and surface tension
1. INTRODUCTION
Nucleate pool boiling phenomenon has attracted
considerable research and practical attention , due to
its ability to transfer large amounts of heat with
relatively small temperature differences. From last 60
years there has been extensive research to address
issues such as bubble growth, bubble dynamics, effects of
heater surface characteristics, fluid -surface interaction,
and fluid properties, among others [1]. In recent years,
due to importance that directed towards the energy
conservation and economic imperatives, much effort
have been made to advance techniques that lead to
enhance nucleate boiling heat transfer.
The extent of enhancement has been found to be
dependent on additive concentrations, its type and
chemistry, wall heat flux, and the heater geometry.
Many studies, have reported the importance of
decreasing the surface tension by adding additives to
the solution and its impact on the boiling heat
transfer coefficient [5].
1.1 Contact angle
It is defined geometrically as the angle formed by a liquid
at the three phase boundary where a liquid, gas and solid
intersect. The measurement of a single static contact angle
to characterize the interaction is no longer thought to be
adequate. For any given solid/ liquid interaction there
exists a range of contact angles which may be found. The
values of static contact angles are found to depend on the
recent history of the interaction. When the drop has
recently expanded the angle is said to represent the
Ǯadvancedǯ contact angle. When the drop has recently
contracted the angle is said to represent the Ǯrecededǯ
contact angle. These angles fall within a range with
advanced angles approaching a maximum value and
receded angles approaching a minimum value. If the three
phase (liquid/solid/vapors) boundary is in actual motion
the angles produced are called Dynamic Contact Angles
and are referred to as Ǯadvancingǯ and Ǯrecedingǯ angles.
The difference between Ǯadvancedǯ and Ǯadvancingǯ,
Ǯrecededǯ and Ǯrecedingǯ is that in the static case motion is
incipient and in the dynamic case motion is actual.
Dynamic contact angles may be assayed at various rates of
speed. Dynamic contact angles measured at low velocities
should be equal to properly measured static angles. In this
test static advanced contact angle is measured. The fig. 1
shows the hoe contact angle is formed on surface at three
boundary layer.