American Journal of Nanomaterials, 2015, Vol. 3, No. 1, 28-39
Available online at http://pubs.sciepub.com/ajn/3/1/4
© Science and Education Publishing
DOI:10.12691/ajn-3-1-4
Synthesis and Mechanical Characterisation of
Aluminium-Copper-Alumina Nano Composites Powder
Embedded in Glass/Epoxy Laminates
P K Dash
1,*
, Prof. B. S. Murty
2
, R B Karthik Aamanchi
3
1
Department of Aeronautical Engineering, IARE, Hyderabad, Telangana
2
Metallurgy & Material Sciences Department, IIT Madras, Chennai, TamilNadu
3
Geetam University, Hyderabad, Telangana
*Corresponding author: drpdash@gmail.com
Received May 06, 2015; Revised June 05, 2015; Accepted July 15, 2015
Abstract This paper presents the synthesis and mechanical properties study of Aluminum-Copper nanocomposite
powders with variation in volume percentages of alumina. The powders were synthesized using mechanical alloying
(high energy ball milling technique). Samples of size 20 × 10 mm were produced from nanocomposite powders by
spark plasma sintering technique and conventional sintering method. The microstructural verifications were carried
out using X-ray diffraction. Transition electron microscopy were used to determine the phases formed and size of the
particles. Thermal analysis and hardness of these samples were measured by conducting DSC and Vickers’s
Hardness Test. Also, the powders of ACANC were embedded into Glass/Epoxy laminates for further identification
of NC powders effects on mechanical properties like tensile and compressive strength. The samples prepared using
conventional sintering technique had gone through two different types of annealing before sintering and shown
enhanced hardness, yield strength and increment in density. The nanocomposite embedded laminates have shown
improved tensile, compression and hardness values in compare to virgin specimens.
Keywords: Al-Cu-Alumina-Nano-Composite (ACANC), plasma sintering technique, X-ray diffraction, TEM, DSC,
GFRC, mechanical properties
Cite This Article: P K Dash, Prof. B. S. Murty, and R B Karthik Aamanchi, “Synthesis and Mechanical
Characterisation of Aluminium-Copper-Alumina Nano Composites Powder Embedded in Glass/Epoxy
Laminates.” American Journal of Nanomaterials, vol. 3, no. 1 (2015): 28-39. doi: 10.12691/ajn-3-1-4.
1. Introduction
Nanocomposite, a high performance material exhibit
unusual property combination and unique design
possibilities [1,2]. With an estimated annual growth rate of
about 25% and fastest demand to be in engineering
plastics and elastomers, their potential is so striking that
they are useful in several areas ranging from packaging to
biomedical applications. Present day, a spurt of research
activity is witnessed in the area of synthesis, fabrication
and utilization studies of different size and shape of metal
nano-particles [1-50]. With polymer NCs, properties
related to local chemistry, degree of thermoset cure,
polymer chain mobility, polymer chain conformation,
degree of polymer chain ordering or crystallinity can all
vary significantly and continuously from the interface
with the reinforcement into the bulk of the matrix [17-31].
Also, it can have an observable effect on the macroscale
properties of the composite [32-50]. For example, adding
carbon nanotubes improves the electrical and thermal
conductivity. Other kinds of nano-particulates may result
in enhanced optical properties, dielectric properties, heat
resistance or mechanical properties such as stiffness,
strength and resistance to wear and damage [10-50].
The metallic NC plays a significant role in modern day
engineering due to its excellent conductivity and low cost
nano-particles [2]. These nanostructural materials can be
synthesized in controlled processes by the methods like,
highly energetic reactive milling, precipitation from
solution (sol-gel), hydrothermal synthesis, electrochemical
synthesis, and internal oxidation etc [1-16]. One of them is
Aluminum Copper alumina nano particles which will gain
increasing importance as is expected to be an essential
component in the future nano-devices due to its excellent
thermal properties as well as good biocompatibility and its
surface enhanced Raman scattering (SERS) activity [3].
Also, the addition of metallic copper nano-crystals,
dispersed homogeneously in silica layers have attracted
great attention recently for the development of nonlinear
optical devices [4].
The most extensively used methods for the production
of Al-Cu-alumina composite materials (ACACMs) are
based on casting, [8] mechanical alloying [9,10] and other
techniques. [11,12] However, conventional casting techniques
are not practical because of the poor uniformity of
dispersed particles. But, ACACMs are increasingly
produced by powder metallurgy (P/M) method where the