International Journal of NanoScience and Nanotechnology.
ISSN 0974-3081 Volume 2, Number 1 (2011), pp. 1-23
© International Research Publication House
http://www.irphouse.com
Investigations on Zinc Doped Nanocrystalline
Hydroxyapatite
G. Devanand Venkatasubbu
1*
, S. Ramasamy
1
, V. Ramakrishnan
2
,
G.S. Avadhani
3
, R. Thangavel
4
and J. Kumar
1
1
Crystal Growth Centre, Anna University, Chennai-600025, Tamil Nadu, India
2
Department of Laser Studies, School of Physics,
Madurai Kamaraj University, Madurai, Tamil Nadu, India
3
Department of Materials Engineering,
Indian Institute of Science, Bangalore-560012-India
4
Research Centre for Applied Sciences, Academia Sinica,
Taipei 115, Taiwan, Republic of China
*Corresponding Author E-mail: gdevanand@gmail.com
Abstract
Hydroxyapatite is a biocompatible and biodegradable material used in the drug
delivery system. Nano hydroxyapatite has been used as an inorganic drug for
many years. In this paper, pure nano and zinc added hydroxyapatite were
synthesized by wet precipitation method. The presence of single phase was
identified by X-ray diffraction. The functional groups present were identified
by FTIR spectroscopy. The samples were investigated using micro Raman
spectroscopy TEM, EDX, XPS and XRF. TEM observations showed needle
shape particles of length up to 100 nm. The addition of zinc in hydroxyapatite
is confirmed by FTIR and micro Raman spectroscopy. Pure hydroxyapatite
powder and zinc added hydroxyapatite powder were palletized under an
uniaxial pressure of 100 MPa and sintered at 900°C for 1 hour. These pellets
were used to investigate the antibacterial activity and Vickers micro hardness
of pure and zinc doped hydroxyapatite powder nanoparticles. Antibacterial
studies showed that pure and zinc doped hydroxyapatite powder have good
antibacterial activity against Pseudomonas aeruginosa and Staphylococcus
aureus. The antibacterial activity and hardness of zinc added hydroxyapatite
was found to increase with increase in the zinc concentration.
Keywords: Hydroxyapatite, Drug delivery, Pseudomonas aeruginosa,
Staphylococcus aureus, Antibacterial activity, Micro hardness.