International Journal of Medicine and Medical Sciences Vol. 2(1), pp. 053-058, January, 2012. Available online at
http://internationalscholarsjournals.org (ISSN: 2167-0404) © International Scholars Journals
Full Length Research Paper
Cytotoxic Effects of Zinc Oxide Nanoflakes (ZNO NFS) in
Human Muscle Carcinoma
Syed M. Usman Ali
1, 4
, M. Fakhar-e-Alam
1, 2
, Z.Wazir
2
,M. Kashif
3
, M. Atif
2
, Magnus Willander
1
and W. A. Syed
2
1
Physical Electronics and Nanotechnology Division, Department of Science and Technology, Campus Norrköping,
Linköping University, SE-60174 Norrköping, Sweden
2
Department of Physics, Faculty of Basic and Applied Sciences, International Islamic University, Islamabad
3
Nano Biochip Research Group, Institute of Nano Electronic Engineering (INEE), University Malaysia Perlis (UniMAP),
01000 Kangar, Perlis, Malaysia.
4
Department of Electronic Engineering, NED University of Engineering and Technology, Karachi-75270, Pakistan
Received October 29, 2011; Accepted January 24, 2012
Cytotoxicity of bare and conjugation of Tween-80 capsulated nanomaterials e.g. zinc oxide nanoflakes
(ZnO NFs), iron oxide nanoparticles (Fe
2
O
3
NPs) was examined in dark as well as under light exposure in
cell model of immature human muscle carcinoma (RD) via microinjection and free standing drug delivery
system. ZnO NFs were grown on the tip of a capillary and characterized by applying atomic force
microscopy (AFM) technique and the tip was used as pointer to insert chemicals into cell to
visualize/assess the emission of reactive oxygen species (ROS) especially from mitochondria. Bare and
conjugated ZnO NFs with δ-aminolevulinic acid (ALA) were irradiated /excited with UV light after cellular
uptake, reactive oxygen species were generated. We deduct that ROS is damaging mitochondria
resulting in cell necrosis within few minutes. ZnO NFs are not biosafe and have significant toxic effects
for both normal as well as cancer cell especially for rhybdomyosarcoma cell line (RD).
Keywords: atomic force microscopy (AFM), δ-aminolevulinic acid (ALA), reactive oxygen species (ROS), human
muscle carcinoma (RD cells), Zinc Oxide nanoflakes ZnO NFs.
INTRODUCTION
Current research suggests that photodynamic therapy
(PDT) is encouraging, minimally invasive treatment
modality for premalignant, malignant lesions requiring
the interaction of light (UV-Visible), photosensitizer, and
singlet oxygen [1]. The basic principle of PDT is to take a
chemical and excite with light (Laser) of specific
wavelength matchable to absorption peak of chemical
drug, leads to the energization of chemicals causing cell
death [2]. Photosensitizer (PS) complexed with
nanomaterials (NMs) activated by UV light (240 nm of
light wavelength) results in tissue necrosis by direct
tumor killing effect, vascular blockade, most importantly
Corresponding author’s E-mail: uashah68@hotmail.com
singlet oxygen release from mitochondria. [3-5].
Nanotechnology or nanoscience is “the design,
characterization, production, and application of
structures, devices, and systems by controlled
manipulation of size and shape at the nanometer scale
(atomic, molecular, and macromolecular scale) which
produces structures, devices, and systems with at least
one novel/superior characteristic or property” [6]. In
addition, Nanomedicine and nanotechnology, have
introduced numerous NPs of variable chemistry and
architecture for cancer diagnostics and treatment,
involving engineering multifunctional devices with
dimensions at the nanoscale [7]. Zinc oxide nanoflakes
(ZnO NFs) and zinc oxide nanowires (ZnO NWs) are
emerging milestones in PDT ongoing research with
tremendous multiple clinical applications, diagnostic as
well as antitumoricidal, in many microbial nonmicrobial