INTRODUCTION
Directional solidification of binary alloys, which allows the
independent control of growth parameters (pulling velocity V,
temperature gradient G, initial solute concentration C
0
), is an
experimental method of choice for the investigation of many
fundamental problems (e.g. microstructure formation and selec-
tion, segregation of chemical species) encountered in the pro-
cessing of structural materials. Two major features should be
noticed. First, solute is rejected in the liquid during the phase
transition when the segregation coefficient k is less than unity
(k is the ratio of the solute concentration in solid to that in liq-
uid), or rejected when k is higher than unity. Consequently,
solidification establishes an exponential solute distribution in
the melt which accompanies the thermal profile imposed to
drive the growth process. Thus, on Earth, the local liquid densi-
ty depends on two fields and convection is almost always pres-
ent in the melt [1]. Second, the planar solid-liquid interface may
undergo the Mullins - Sekerka instability [2] which leads to the
formation of cells and dendrites. Those patterns are described
by shape parameters (primary and secondary spacings, tip
radius …) and characteristic relationships have been proposed
to relate the shape parameters to the processing conditions when
the transport of heat and chemical species is dominated by dif-
fusion [3]. Actually, natural buoyancy-driven convection often
plays an important role in terrestrial solidification processing by
interacting with the microstructure and modifying the relation-
ships. Moreover, between the fully solid and liquid phases the
solid microstructure forms a solid-liquid zone called “mushy
zone”, where the phase transition begins and progressively gets
complete. For fluid mechanics, this mushy zone can be consid-
ered as an intermediate porous medium whose internal structure
is composed of fine-scale crystals, through which residual melt
flows [4].
In Bridgman solidification, one way to prevent thermosolutal
convection is to solidify in a both thermal (i.e. vertical upward
solidification) and solutal (i.e. rejected solute denser than sol-
© Z-Tec Publishing, Bremen Microgravity sci. technol. XVI
B. Billia, H. Nguyen Thi et al: Tailoring of Dendritic Microstructure in Solidification Processing by Crucible Vibration/ Rotation
15
___________
Mail Address:
1)
L2MP, University Aix-Marseille III, Marseille, France
2)
National Microgravity Laboratory, CAS, Beijing, China
3)
Institute of Continuous Media Mechanics UB RAS, Perm, Russia
4)
Laboratoire de Modélisation en Mécanique, Marseille, France
5)
Department of Chemical Engineering, National Taiwan University, Taiwan
Tailoring of Dendritic Microstructure
in Solidification Processing by
Crucible Vibration / Rotation
B. Billia
1
, H. Nguyen Thi
1
, G. Reinhart
1
, Y. Dabo
1
, B.H. Zhou
1,2
,
Q.S. Liu
2
, T.Lyubimova
3
, B. Roux
4
, C.W. Lan
5
Directional solidification of alloys, which allows the independ-
ent control of growth parameters (pulling velocity, temperature
gradient), is an experimental method of choice for the investi-
gation of many fundamental problems (e.g. microstructure for-
mation and selection, segregation of chemical species) encoun-
tered in the processing of structural materials. Upward direc-
tional solidification is carried out on hypoeutectic Al-Ni alloys,
under natural and controlled fluid-flow conditions. First, the
influence of natural convection on solidified dendritic
microstructure is analyzed as a function of growth parameters.
Then, directional solidification experiments with axial vibration
are performed. It results that crucible vibration can be used to
either damp or control fluid flow in the melt, and thus tailor
columnar or "equiaxed" dendritic mush. Advanced modeling
and numerical simulation are essential to clarify and quantify
the various physical effects. Microgravity benchmark experi-
ments under diffusion transport, and possibly with crucible
rotation, are foreseen using the Materials Science Laboratory of
ESA on ISS.