Agriculture, Forestry and Fisheries
2013; 2(3): 116-125
Published online May 30,2013 (http://www.sciencepublishinggroup.com/j/aff)
doi: 10.11648/j.aff.20130203.11
Biomobilization of heavy metals from the sediments affect
the bacterial population of Al-Ghadir River (Lebanon)
Amale Mcheik
1, 2,
*, Mohamad Fakih
1, 2
, Noureddine Bousserrhine
1
, Joumana Toufaily
2, 3
,
Evelyne Garnier-Zarli
1
, Taysir Hamieh
2
1
Paris-Est University, Créteil, France
2
Lebanese University, Hadath, Beirut, Lebanon
3
School of Mechanical and Materials Engineering, Washington State University, Pullman, WA 99164, United States of America
Email address:
Amale.am@hotmail.com(A. Mcheik), fakih.mohamad@gmail.com(M. Fakih), bousserrhine@u-pec.fr(N. Bousserrhine),
joumana.toufaily@ul.edu.lb(J. Toufaily), garnier@u-pec.fr(E. Garnier-Zarli), tayssir.hamieh@ul.edu.lb(H. Taysir)
To cite this article:
Amale Mcheik, Mohamad Fakih, Noureddine Bousserrhine, Joumana Toufaily, Evelyne Garnier-Zarli, Taysir Hamieh. Biomobilization of
Heavy Metals from the Sediments Affect the Bacterial Population of Al-Ghadir River (Lebanon). Agriculture, Forestry and Fisheries.
Vol. 2, No. 3, 2013; pp. 116-125.doi: 10.11648/j.aff.20130203.11
Abstract: Although there is no doubt about the importance of the bacterial activity on the solubilisation and the distribution
of heavy metals in aquatic sediments, hydromorphic soils and ground waters; little is known about the involvement of
bacterial dissolution in periodically anaerobic environments like that found in dredged sediments and little is known about the
processes and the environmental factors controlling this process.The aim of this paper was to study the effect of the
autochthonous bacterial activity on the biodegradation of organic matter and the mobilization of heavy metals in the
sediments of Al-Ghadir river (Mount Lebanon). Sediments were incubated under standard anaerobic conditions and enriched
with glucose to stimulate and accelerate microbial metabolism. The evolution of carbon metabolism (Organic matter evolved,
carbon consumed and organic acids produced) and metals released in batch reactors were followed over time. Under the
adopted conditions, analysis of the chemical parameters indicated that the incubated sediments showed a significant release
of organic carbon corresponding to bacterial development. Mineral analysis showed an important solubilisation of Fe
2+
and
Mn
2+
indicating the presence of Fe- and Mn-reducing bacteria in sediments. Pb, Cd and Cr solubilisation profiles were
observed and appeared concomitant to the solubilisation profiles of Fe and Mn indicating that the redox cycle has been well
installed and that Pb, Cd and Cr were associated to Fe and Mn oxides. The production of Cu appeared in parallel to the
mineralization of the organic matter in the sediment indicating that Cu was associated to this fraction. Zn appeared associated
to the sulphide fraction than to the Fe and Mn oxides fraction. Microbiological and genetic analysis showed a decrease and
the disappearance of some bacterial strains due to the shift in the culture conditions and the toxicity of the released heavy
metals but at the same time the development and the growth of many other populations which showed to be tolerant to the
same conditions.
Keywords: Mobilization of Heavy Metals, Incubated River Sediments, Fe- and Mn-Reducing Bacteria
1. Introduction
The biogeochemical cycle of heavy metals has been
greatly accelerated by human activities. Heavy metals enter
the ecosystem through both natural and anthropogenic
processes. Some soils have been found to have a high
background of some trace elements which are toxic to
plants and wildlife.
Anthropogenic processes include inputs of heavy metals
from industrial and municipal effluents, land-fill leaching,
non-point source run-off, and atmospheric deposition [1, 2].
When these metals discharge to the aquatic environment,
the metal is partitioned between the sediment and the water
column phases. Further partitioning of metals occurs within
the sediment chemical fractions and metal speciation occurs
in water column with different ligands [3, 4]. This process
of metal speciation may lead to the self-purification of
rivers from metal pollution.
Accumulation of these heavy metals in different
compartments of the environment, and particularly in the
river sediments, and their possible mobilization under
environmentally changing conditions induce a perturbation