390 Int. J. Microstructure and Materials Properties, Vol. 7, No. 5, 2012
Copyright © 2012 Inderscience Enterprises Ltd.
Influence of loading rates on morpholgy and
mechanical properties of PLA/clay nanocomposites
Mustapha Kaci* and Lynda Zaidi
Laboratory of Organic Materials,
Department of Engineering Processes,
Faculty of Technology,
University Abderrahmane Mira,
Route de Targa-Ouzemmour,
Bejaia 06000, Algeria
Fax: +21334215105
E-mail: kacimu@yahoo.fr
E-mail: sinda_77@yahoo.fr
*Corresponding author
Stéphane Bruzaud, Alain Bourmaud,
Pascal Médéric and Yves Grohens
Laboratoire d’Ingénierie des Matériaux de Bretagne,
Université de Bretagne Sud,
56321 Lorient Cedex, France
E-mail: stephane.bruzaud@univ-ubs.fr
E-mail: alain.bourmaud@univ-ubs.fr
E-mail: pascal.mederic@univ-brest.fr
E-mail: yves.grohens@univ-ubs.fr
Abstract: This paper reports some experimental results on the influence of
loading rates on morphology and mechanical properties of clay nanocomposites
based on polylactide (PLA). The dispersed phase was organically modified
montmorillonite commercially known as Cloisite 30B and introduced at various
loading rates: 1, 3 and 5 wt.%. The nanocomposites were prepared by melt
intercalation in a Brabender Plasticorder mixer. Wide angle X-ray scattering
showed that the clay was finely distributed in the PLA matrix and the
nanocomposite morphology can be considered as intercalated/exfoliated
structure, whatever the filler content. The effect of clay loadings on the
mechanical properties of PLA/organoclay was investigated by nanoindentation
and tensile measurements. Nanoindentation results showed a significant
improvement in modulus and hardness with increase of the clay contents. This
is consistent with the large increase in Young’s modulus obtained by tensile
tests indicating a good correlation of mechanical properties at the macrometric
and nanometric scales.
Keywords: polylactide; PLA; clay; nanocomposites; melt intercalation;
morphology; mechanical properties; wide angle X-ray scattering;
nanoindentation.