EXPERIMENTAL INVESTIGATION OF THE INSTABILITY OF BUCKLING PATTERNS: FROM STRAIGHT-SIDED TO WORMLIKE STRUCTURES F. Cleymand, C. Coupeau and J. Grilhe ´ Laboratoire de Me ´tallurgie Physique, UMR 6630, SP2MI, Bld P. & M. Curie 86962, Futuroscope Cedex, France (Received January 30, 2001) (Accepted February 8, 2001) Keywords: Atomic force microscopy (AFM): Thin films, Wrinkling Introduction The understanding of the mechanical properties of coated materials is a key factor in a number of technological applications. In particular, the delamination of compressed thin films is one of most limiting structural performance and presents various interesting problems in physics and mechanics. The delamination of compressed thin films has been investigated by many experimental and theoretical studies [1–5]. The delamination patterns result from high residual compressive stresses in the thin film mainly due to the deposition process and involve the propagation from an initial buckle of cracks at the film/substrate interface [6 –9]. Various shapes of debonding patterns, such as straight-sided blisters [10] or worm-like structures [4], have been observed and characterised in different film/ substrate specimens. The worm-like buckling patterns are elongated tunnels with antisymmetric undulation at the edges and have been recently simulated by Crosby and Bradley [11]. Recently, the linear stability of straight delamination patterns has been performed by a numerical resolution of the Fo ¨ppl and van Karman equations by a perturbation method [12]. One of the results is the determination of a critical value of the Poisson’s ratio allowing the selection of stable configuration between the antisymmetric and symmetric (or varicose) patterns. Nevertheless, this study is based essentially on earlier experimental investigations of pre-existing worm-like blisters, explained by a simple mechanism of instability affecting the propagation of straight-sided ones. Up to the present, the worm-like formation has not been considered as an ageing effect. In this paper, the evolution from straight-sided to worm-like patterns has been studied experimen- tally by atomic force microscopy (AFM). Experimental Results Experiments were conduced on well-adhering 304L Stainless Steel (SS) films 58 nm thick on polycarbonate substrates. The choice of this substrate depends on its elastic behaviour over a wide range of strain, so that no activation of Frank-Read sources takes place. The residual stresses i of the as-deposited thin films before deformation were estimated by the curvature method to be of the order of 1-2 GPa. The specimen has been deformed by uniaxial compression to generate straight-sided blisters perpendicular to the compression axis (Fig. 1a) [13,14]. Scripta mater. 44 (2001) 2623–2627 www.elsevier.com/locate/scriptamat 1359-6462/01/$–see front matter. © 2001 Acta Materialia Inc. Published by Elsevier Science Ltd. All rights reserved. PII: S1359-6462(01)00969-1