Hindawi Publishing Corporation
International Journal of Corrosion
Volume 2013, Article ID 739841, 7 pages
http://dx.doi.org/10.1155/2013/739841
Research Article
Corrosion Response of Ti6Al4V and Ti15Mo Dental Implant
Alloys in the Presence of Listerine Oral Rinse
Rahul Bhola,
1
Charu Chandra,
2
Faisal M. Alabbas,
1,3
Sukumar Kundu,
1,4
Brajendra Mishra,
1
and David L. Olson
1
1
Department of Metallurgical and Materials Engineering, Colorado School of Mines, Golden, CO 80401, USA
2
Department of Chemistry, University of Delhi, Delhi 110007, India
3
Department of Inspection, Saudi Aramco, Dhahran 31311, Saudi Arabia
4
Department of Metallurgy and Materials Engineering, Bengal Engineering and Science University, Shibpur, Howrah 711103, India
Correspondence should be addressed to Rahul Bhola; bhola.rahul@gmail.com
Received 18 July 2013; Accepted 7 October 2013
Academic Editor: Sebastian Feliu
Copyright © 2013 Rahul Bhola et al. his is an open access article distributed under the Creative Commons Attribution License,
which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
he inluence of a commonly used antibacterial mouth rinse, Listerine, on the corrosion behavior of one of the commonly used
titanium alloys Ti6Al4V (two-phase structure, i.e., and ) and a newer Ti15Mo (single phase) in normal saline solution has
been investigated using electrochemical techniques. Interfacial electrochemical changes occurring at the oxide-solution interface
have been analysed using EIS circuit modeling. Listerine acts as a corrosion inhibitor for Ti15Mo alloy and a corrosion promoter
for Ti6Al4V alloy.
1. Introduction
Listerine is a commonly used mouth rinse with antiplaque,
anticaries, and antibacterial properties. It is used in several
dental applications following periodontal procedures and
routine oral prophylaxis. It was awarded the American Dental
Association’s seal of recognition in 1987 for its clinical eicacy
in plaque control and gingival improvement [1].
Listerine antiseptic, developed by Warner-Lambert, was
the irst over-the-counter mouth rinse [2]. Listerine con-
tains diferent essential oils, which are phenolics such as
thymol, eucalyptol, menthol, and methyl salicylate and are
known to retard plaque buildup and reduce gingivitis [3–
10]. hymol, eucalyptol, and menthol are known to possess
proven antibacterial activity and are found in thyme (hymus
vulgaris), eucalyptus (Eucalyptus globulus), and peppermint
(Mentha piperita), respectively. Methyl salicylate has anti-
inlammatory activity and is found in meadowsweet (Fil-
ipendula ulmaria) and willow (Salix spp.) [2]. he efect of
Listerine on plaque was ascribed to its bactericidal properties
related to the alteration of bacterial cell wall, which has been
well documented in vitro and in vivo [11–15].
A newly inserted prosthesis and various surrounding
tissues may get exposed to Listerine from minutes to days,
depending upon the therapy performed and the local and
systemic patient factors. It is thus important to understand
the efect of Listerine on the electrochemical and corrosion
behavior of titanium alloys in order to predict treatment
prognosis. Cestarolli et al. [16] have compared the efect of
mouthwashes including Listerine and a simulated body luid
on the corrosion behavior of an Fe-Cr-Ni alloy. he corrosion
resistance of this alloy was the highest in the presence of Lis-
terine mouthwash. However, the present study simulates the
use of Listerine as an oral prophylactic rinse, in other words,
the condition when the concentration of saliva gets altered
due to the presence of Listerine in the mouth. he efect of
this normal saline-Listerine solution has, thus, been explored
on the behavior of titanium alloys when used as prostheses
in patients. he conventional dental implants comprise the
Ti6Al4V alloy but owing to its higher modulus of elasticity
and thereby creating a greater modulus mismatch with the
bone (stress shielding efect) newer beta alloys, Ti15Mo, with
lower elastic modulus are being developed for use as implants
in oral cavity.