Research Article Open Access
Gude et al., J Microbial Biochem Technol 2013, S6
http://dx.doi.org/10.4172/1948-5948.S6-005
Research Article Open Access
Microbial & Biochemical Technology
J Microb Biochem Technol ISSN:1948-5948 JMBT, an open access journal
Biofuel Cells and
Bioelectrochemical systems
*Corresponding author: Venkataramana Gadhamshetty, Environmental
Engineering, Florida Gulf Coast University, USA, Tel: 1 239 590 7647; Fax: 1 239
590 7801; E-mail: vgadhamshetty@fgcu.edu
Received April 01, 2013; Accepted July 23, 2013; Published July 26, 2013
Citation: Gude VG, Kokabian B, Gadhamshetty V (2013) Beneicial
Bioelectrochemical Systems for Energy, Water, and Biomass Production. J Microb
Biochem Technol S6: 005. doi:10.4172/1948-5948.S6-005
Copyright: © 2013 Gude VG, et al. This is an open-access article distributed under
the terms of the Creative Commons Attribution License, which permits unrestricted
use, distribution, and reproduction in any medium, provided the original author and
source are credited
Abstract
The major insecurities facing the modern world are tied to depleting fuel reserves and rising greenhouse gas
emissions. A quest for clean and renewable fuels has invigorated research efforts in both developed and developing
countries. Microbial Fuel Cell (MFC) technology has been promoted as an innovative application of microbes for
producing sustainable energy from organic waste streams emerging from a variety of waste sources. The latest
scientiic discoveries in MFC technology provide a framework for multitude of MXC technologies, ranging from
Microbial Desalination Cells (MDCs) used in desalination of brackish water; Microbial Electrolysis Cells (MECs) used
for production of hydrogen; and microbial solar cells (MSCs) for sequestration of carbon dioxide from atmospheric
and anthropogenic sources. The MXCs demonstrate a potential for sustainable water treatment and clean energy
production under environmentally benign conditions. This article provides a critical overview of MXCs with a special
focus on MDCs.
Beneficial Bioelectrochemical Systems for Energy, Water, and Biomass
Production
Veera Gnaneswar Gude
1
, Bahareh Kokabian
1
and Venkataramana Gadhamshetty
2
*
1
Civil and Environmental Engineering, Mississippi State University, USA
2
Environmental Engineering, Florida Gulf Coast University, USA
Keywords: Microbial Fuel cells, Desalination, Sustainable Energy,
Microbial Desalination Cells, Microbial Solar Cells, Algae
Introduction
Microbial fuel cells (MFCs) operate in a galvanic mode: they
employ microbial catalysts to extract oxidation current from waste
organic matter in the anodic half-cell; and use chemical catalysts in the
cathodic half-cell to consume electrons in the presence of protons and
terminal electron acceptor. he anode can be designed for treatment of
municipal waste streams, and high-strength organic wastes emerging
from cattle farms, breweries, landills, chocolate factories, and food
processors[1-6] while the reducing conditions in the cathodic half-
cell provide a legitimate route for treating oxidized contaminants (e.g.
nitrates and chromium)in water bodies [7]. he cathodes have been
demonstrated for treatment of perchlorate [8], uranium (UVI) [9],
and chlorinated compounds (e.g. chloro ethene, 2-chlorophenol, and
pentachlorophenol) [10,11]. MXCs refer to new bioelectrochemical
systems that share the principles of MFCs, with a slight variation in
the anode and/or cathode coniguration. For instance, Microbial
desalination cell (MDC) is a variant of MFC which includes an
additional middle chamber for sustainable energy production (from
organic wastes) and water desalination. he MDCs can be designed for
treatment of organic waste and simultaneous desalination of saltwater
[12].
Other versions of MXCs include microbial electrolysis cell (MECs),
microbial reverse-electrodialysis cell (MRC), and microbial solar cell
(MSC). he MRCs produce electric power from entropic energy based
on the salinity diference between seawater and river water [13]; the
MECs deliver hydrogen, or methane from organic wastes [14,15]; MSCs
use photosynthetic bacteria to convert solar energy into electricity [16],
all with the aid of tiny microbes and sustainable waste matter.
Modest amount of literature exists in the domains of microbial fuel
cell research. Palmore and White sides summarized biological fuel cell
concepts and performance up to 1992. Logan provided detailed review
on the basic operation, materials, and architecture of MFC technology
upto 2007 [17]. Details on the scale-up prospects of MFC technology
have been recently reported in the scientiic literature [18]. Torres et
al. reported a perspective on extracellular electron transfer by anode-
respiring bacteria [19]. Venkatamohan et al. have investigated the
performance of MFCs with non-catalyzed MFCs [20]. Rabaey and
Verstraete discussed the aspects of electron transfer, metabolism and
energy losses in MFCs [21]. A state of the art review on MFC technology
for wastewater treatment has been provided by Du et al. [22]. He et
al. [7] provided comprehensive details on the experimental progress
of biocathodes in microbial fuel cells (MFCs). Rabaey & Verstraete
[21] described the mechanisms of electron transfer in the anode, while
Rishman-Yazdi et al. [23] summarized the factors relevant to cathodic
limitations in MFCs. Pham et al. provided a critical comparison of the
conventional AD technology and the MFC technology [24]. Schroder
et al. discussed the electron transfer processes in MFCs [25,26]. Kim
and Logan published a irst review article that describes the research
progress of microbial desalination technology [12]. his article does
not replicate these valuable contributions, and instead, updates recent
advances on emerging MXCs that build upon the R&D framework of
MFC technology. his article focuses on the development of microbial
desalination cell and microbial solar cell technology in recent years.
A Brief History on Mxcs
During 18
th
century, Luigi Galvani provided the irst experimental
evidence on bioelectricity by recording the electric response obtained
from connecting frog legs to a metallic conductor [27]. In 1911, Michael
C. Potter demonstrated the electric current production through
microbial oxidation of non-electrolytes (e.g organic compounds) [28].
In 1931, Barnett Cohen reconirmed Potter’s results by producing
0.2 mA current by poising a half cell at +0.5 V using a potentiostat