Accepted Manuscript Title: A DFT Study of the Mechanism of Palladium-Catalyzed Alkoxycarbonylation and Aminocarbonylation of Alkynes: Hydride versus Amine Pathways Authors: Rami Suleiman, Abdelletif Ibdah, Bassam El Ali PII: S0022-328X(11)00140-9 DOI: 10.1016/j.jorganchem.2011.02.027 Reference: JOM 17017 To appear in: Journal of Organometallic Chemistry Received Date: 20 October 2010 Revised Date: 11 January 2011 Accepted Date: 23 February 2011 Please cite this article as: R. Suleiman, A. Ibdah, B. El Ali. A DFT Study of the Mechanism of Palladium- Catalyzed Alkoxycarbonylation and Aminocarbonylation of Alkynes: Hydride versus Amine Pathways, Journal of Organometallic Chemistry (2011), doi: 10.1016/j.jorganchem.2011.02.027 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain.