Use of neutralized industrial residue to stabilize trace elements
(Cu, Cd, Zn, As, Mo, and Cr) in marine dredged sediment from
South-East of France
Mehwish Taneez
a, *
, Nicolas Marmier
a
, Charlotte Hurel
b
a
Universit e Nice Sophia Antipolis, CNRS, FRE 3729 ECOMERS, Parc Valrose 28, Nice, 06108, France
b
Universit e Nice Sophia Antipolis, CNRS, LPMC, UMR 7336, Parc Valrose, 06108 Nice, France
highlights
Bauxite residue (bauxaline
®
) was neutralized with gypsum to lower its pH.
Neutralized bauxaline
®
was used as amendment at 5% and 20% for trace elements stabilization in marine dredge sediment.
20% neutralized bauxaline
®
immobilized significantly cationic pollutants.
Leachates toxicity towards rotifers (Brachionus plicatilis) was sufficiently decreased with 20% amendment application.
article info
Article history:
Received 29 September 2015
Received in revised form
13 January 2016
Accepted 2 February 2016
Available online xxx
Handling Editor: Martine Leermakers
Keywords:
Neutralized bauxaline
®
Gypsum addition
Trace elements
Marine dredged sediment
Stabilization
Ecotoxicity
abstract
Management of marine dredged sediments polluted with trace elements is prime issue in the French
Mediterranean coast. The polluted sediments possess ecological threats to surrounding environment on
land disposal. Therefore, stabilization of contaminants in multi-contaminated marine dredged sediment
is a promising technique. Present study aimed to assess the effect of gypsum neutralized bauxaline
®
(bauxite residue) to decrease the availability of pollutants and inherent toxicity of marine dredged
sediment. Bauxaline
®
, (alumia industry waste) contains high content of iron oxide but its high alkalinity
makes it not suitable for the stabilization of all trace elements from multi-contaminated dredged sedi-
ments. In this study, neutralized bauxaline
®
was prepared by mixing bauxaline
®
with 5% of plaster.
Experiments were carried out for 3 months to study the effect of 5% and 20% amendment rate on the
availability of Cu, Cd, Zn, As, Mo, and Cr. Trace elements concentration, pH, EC and dissolved organic
carbon were measured in all leachates. Toxicity of leachates was assessed against marine rotifers Bra-
chionus plicatilis. The Results showed that both treatments have immobilization capacity against different
pollutants. Significant stabilization of contaminants (Cu, Cd, Zn) was achieved with 20% application rate
whereas As, Mo, and Cr were slightly stabilized. Toxicity results revealed that leachates collected from
treated sediment were less toxic than the control sediment. These results suggest that application of
neutralized bauxaline
®
to dredged sediment is an effective approach to manage large quantities of
dredged sediments as well as bauxite residue itself.
© 2016 Elsevier Ltd. All rights reserved.
1. Introduction
The presence of contaminants in aquatic environment has
attracted global attention in the recent years due to their toxicity,
abundance and persistence (Sin et al., 2001). Trace elements can be
easily adsorbed onto particles, deposited and accumulated in the
sediments, making sediments a sink and an ultimate source of
contaminants. Contaminants can be released back into water col-
umn during natural (tidal movements or storms) and anthropo-
genic processes (dredging, dredged disposal and fishing) that
provoke little variations of pH or redox potential of interstitial
water (Calmano et al., 1996; Zoumis et al., 2001; Eggleton and
Thomas, 2004). Mediterranean Sea is vulnerable to chemical
contamination due to its semi-closed environment with low
freshwater inputs. During the past decades, industrial, agricultural
and urban waste have been discharged into the Mediterranean Sea
* Corresponding author.
E-mail address: mehtaneez@gmail.com (M. Taneez).
Contents lists available at ScienceDirect
Chemosphere
journal homepage: www.elsevier.com/locate/chemosphere
http://dx.doi.org/10.1016/j.chemosphere.2016.02.014
0045-6535/© 2016 Elsevier Ltd. All rights reserved.
Chemosphere 150 (2016) 116e122