Improved Cole-Cole Parameter Extraction from Frequency Response Using Least Squares Fitting Todd J. Freeborn, Brent Maundy, and Ahmed Elwakil* Department of Electrical and Computer Engineering, University of Calgary, Calgary, Alberta, Canada. *Department of Electrical and Computer Engineering, University of Sharjah, P.O. Box 27272, Emirates (elwakil@ieee.org). Abstract—In this paper we propose using a method of non-linear least squares to extract the Cole-Cole impedance parameters (Ro, R, α, τ ) from collected frequency response datasets. We show how this method reduces the error of the extracted parameters when compared to direct extraction methods whose accuracy are limited by the measured low and high frequency gains. Parameters extracted using the non-linear least squares show up to 4 orders of magnitude lower relative error from ideal simulated datasets compared to direct methods. Experimentally extracted parameters from fruit tissue frequency responses verify the accuracy of the proposed non-linear least squares method over the direct extraction method. I. I NTRODUCTION Fractional calculus, the branch of mathematics dealing with differentiation and integration to non-integer order, has tradition- ally been the domain of theoretical pursuits by mathematicians. With a fractional derivative of order α given by the Grünwald- Letnikov approximation [1] below a D α f (x) lim h0 1 h α [ x-a h ] m=0 Γ(α + 1) m!Γ (α m + 1) f (x mh) (1) While there are no physical analogies to these derivatives, like slope or area under a curve, the concepts of fractional calculus and fractional-order systems show many useful appli- cations in diverse fields of engineering. A few of these include materials theory [2], control theory [3], electronic filters [4], bioimpedance measurements [5], [6], [7] and more emerging regularly. In the field of bioimpedance measurements, the Cole-Cole impedance model [8] is widely used for characterizing biologi- cal tissues and biochemical materials [9] because of its simplic- ity and good fit with measured data illustrating the behaviour of tissue impedance as a function of frequency. The Cole-Cole model is composed of three hypothetical circuit elements: a high-frequency resistor R , a low-frequency resistor R o , and a constant phase element (CPE). The CPE’s impedance is given as Z CPE =1/() α C ; C is the capacitance and α is its order, where 0 1. The expression for the impedance of the Cole-Cole model is given as Z = R + R o R 1+(jωτ ) α = Z + jZ ′′ (2) where τ is the time constant given by τ = [(R o R ) C ] 1 . Research has shown that the impedance parameters of healthy and cancerous tissues differ [10]. Therefore, the accurate mea- surement of these characteristics has the potential to aid doctors + - + - + - + - - - + + (a) (b) Figure 1. Circuits for (a) filter and (b) integrator extraction of the Cole-Cole model parameters. and researchers in the diagnosis and study of cancerous tissues. To characterize a particular tissue requires the determination of the four parameters R o ,R , α, and τ . The traditional method to extract these parameters is to measure the tissue impedance and construct a plot relating the imaginary impedance Z ′′ to the real impedance Z from which the four parameters can be graphically extracted. Recent work has shown two techniques to extract the parameters requiring only the frequency response without direct measurement of the impedance and has been presented in [6] and [7]. In this paper, we propose using a method of non-linear least squares fitting (NLSF) to extract the Cole-Cole impedance parameters from collected frequency response datasets. We show how the methods presented in [6] and [7] are sensitive to the accuracy of select measurements from a collected dataset, while the NLSF method reduces the error in the extracted parameters. The Cole-Cole impedance parameters are extracted from MATLAB simulated datasets and experimentally collected fruit tissue datasets verifying the improved accuracy of this proposed method. II. ANALYSIS OF DIRECT EXTRACTION METHOD In [6] and [7] a Cole-Cole impedance is used as a component in the extraction circuits; shown in Figs. 1(a) and (b), respec- tively, exhibiting the frequency responses described by T 1 (s) = V o (s) V in (s) = 1 G 1 1+(τs) α 1+ G2 G1 (τs) α (3) T 2 (s) = V o (s) V in (s) = G 1 + G 2 (τs) α 1+(τs) α (4) where T 1 (s) and T 2 (s) are the filter and integrator transfer functions, respectively. G 1,2 are the low and high frequency 978-1-4673-0219-7/12/$31.00 ©2012 IEEE 337