Desalination 195 (2006) 109–118
0011-9164/06/$– See front matter © 2006 Elsevier B.V. All rights reserved
*Corresponding author.
Wastewater reclamation by advanced treatment of secondary
effluents
M. Petala
a
, V. Tsiridis
a
, P. Samaras
b
*, A. Zouboulis
c
, G.P. Sakellaropoulos
a
a
Chemical Process Engineering Laboratory, Department of Chemical Engineering, Aristotle University of Thessaloniki
and Chemical Process Engineering Research Institute, 57001 Thermi-Thessaloniki, Greece
b
Department of Pollution Control Technologies, Technological Educational Institute of Western Macedonia,
50100 Kozani, Greece
Tel. +30 (24610) 40161; Fax +30 (24610) 39682; email: psamaras@kozani.teikoz.gr
c
Division of Chemical Technology, Department of Chemistry, Aristotle University of Thessaloniki,
54124 Thessaloniki, Greece
Received 4 May 2005; accepted 17 October 2005
Abstract
The objectives of this study were the investigation of the performance of an advanced treatment system, for the
reclamation of secondary municipal effluents, and the study of the environmental quality of treated effluents. The
secondary effluents from a conventional activated sludge process were fed to an advanced wastewater treatment
system, consisting of a moving-bed sand filter, a granular activated carbon adsorption bed and ozone disinfection.
The performance of this plant was evaluated by measuring the physicochemical, microbiological and ecotoxicological
characteristics of reclaimed water. Sand filtration resulted in about 45% turbidity removal, while carbon adsorption
enhanced mainly the removal of organic content, i.e. the total organic carbon removal exceeded 80%. The quality
of treated effluents, obtained after ozonation by an ozone dosage of 26.7 mg/L, was found to comply with the
respective US EPA proposed guidelines for urban reuse, food crop irrigation and recreational impoundments.
However, a high ozone dose caused adverse effects on bacterium V. fischeri, possibly due to the formation of
secondary oxidation byproducts. The annual cost of overall tertiary treatment process was evaluated to 0.24 €/m
3
,
indicating the relatively high cost of these processes. Nevertheless, such processes are required in order to produce
an effluent, with a high reuse potential.
Keywords: Tertiary treatment; Reuse; Reclamation; Filtration; Ozonation; Ecotoxicity