Proceedings of the
International Conference on Mechanical Engineering 2009
(ICME2009) 26- 28 December 2009, Dhaka, Bangladesh
ICME09-AM-12
© ICME2009 1 AM-12
1. INTRODUCTION
Fiber reinforced polymer matrix composites due to
their high specific strength and specific stiffness to
weight ratios have become attractive structural materials
in aerospace industry, marine, armor, automobile,
railways, civil engineering structures, sport goods etc.
[1]. The incorporation of inorganic fillers has proved to
be an effective way of improving the mechanical and
thermal properties of these materials. However, the
typical filler content needed for significant enhancement
of these properties can be as high as 10-20% by volume.
The processing of the materials often becomes difficult
at such high particle volume fractions due to the higher
density of the inorganic filler than the resin and the
increased density of the filled resin [2]. In this rationale,
nanoparticles such as CNFs, CNTs, clay, metallic
nanoparticles filled fiber reinforced polymer matrix
composites are attracting considerable attention since
they can enhance properties that are sometimes even
higher than the conventional filled polymers composites
at volume fractions in the range of 1 to 5%.
Improvements in mechanical, electrical, and
chemical properties have resulted in major interest in
nanocomposite materials in numerous automotive,
aerospace, electronics and biotechnology applications.
These nanoscale materials provide the opportunity to
explore new behavior and functionality beyond those
found in conventional materials. It has been established
that the addition of small amounts of nanoparticles (<5
wt. %) to a matrix system can increase thermal and
mechanical properties without compromising the weight
or process-ability of the composite [3]. The higher
surface area is one the most promising characteristics of
the nanoparticles due to its ability of creating a great
interface in a composite. An interphase of 1 nm thick
represents roughly 0.3% of the total volume of polymer
in the case of micro particle filled composites; whereas
it can reach 30% of the total volume in the case of
nanocomposites [4]. Contribution made by the
interphase modified by the low nanofiller loading
provides possibilities of enhanced performance by
reinforced composites with a small percentage of strong
fillers can significantly improve the mechanical,
thermal, and barrier properties of the pure polymer
matrix [6].
Choi et al. [7] have fabricated and studied the
Epoxy/CNF composite with different proportions of
CNFs by the in situ process modifying both low and
high viscous epoxies. The SEM images showed a high
level of dispersion for all materials, although occasional
small aggregates were observed in high viscosity epoxy
of 20 wt%. The storage modulus and T
g
of the polymer
were increased by incorporation of CNFs. The results
showed the maximum tensile strength and Young’s
modulus at 5 wt% of CNF and reduction of the fracture
strain with increasing filler content. Mechanical,
electrical and thermal properties of low viscosity epoxy
composites were resulted better than that of the high
viscosity composites. Hussain et al. [8] have
investigated the effect of nanoscale Al
2
O
3
particles in
filament wound carbon fiber/epoxy composites and
found an increase in modulus, flexural strength,
MECHANICAL AND THERMAL CHARACTERIZATION OF CNF-
FILLED POLYESTER NANOPHASED COMPOSITE
Mohammad Kamal Hossain, Muhammad Enayet Hossain, Mahesh Hosur and Shaik Jeelani
Tuskegee University, Tuskegee, USA
ABSTRACT
A high intensity ultrasonic liquid processor was used to infuse carbon nanofibers (CNFs) into polyester
matrix which was then mixed with catalyst using a high speed mechanical agitator. Results showed the
significant improvement in the dispersion of CNFs in sonication over the mechanical mixing method.
Flexure tests performed on the neat polyester (NP), 0.1wt. %, 0.2 wt.%, 0.3 wt.% and 0.4 wt.% CNF-
filled polyester (CNF-FP) showed 86% and 16% increase in flexural strength and modulus, respectively,
compared to the unfilled polyester with increasing loading percentage of CNF up to 0.2%. Similar trend
was found with CNF-filled glass reinforced polyester (CNF-FGRP) composites manufactured by vacuum
assisted resin transfer molding (VARTM). Dynamic mechanical analysis (DMA) studies indicated an
increasing trend of storage modulus and glass-transition-temperature (T
g
) values of all nanophased
composites compared to neat polyester. Scanning electron microscopy (SEM) micrographs of fracture
surfaces revealed relatively smooth surface of neat polyester compared to the nanophased polyester.
Keywords: Polyester, CNF, Mechanical and Thermal Properties.