Open Journal of Biophysics, 2016, 6, 1-9
Published Online January 2016 in SciRes. http://www.scirp.org/journal/ojbiphy
http://dx.doi.org/10.4236/ojbiphy.2016.61001
How to cite this paper: Ali, I.M., Ibrahim, I.M., Ahmed, E.F. and Abbas, Q.A. (2016) Structural and Characteristics of Man-
ganese Doped Zinc Sulfide Nanoparticles and Its Antibacterial Effect against Gram-Positive and Gram-Negative Bacteria.
Open Journal of Biophysics, 6, 1-9. http://dx.doi.org/10.4236/ojbiphy.2016.61001
Structural and Characteristics of Manganese
Doped Zinc Sulfide Nanoparticles and Its
Antibacterial Effect against Gram-Positive
and Gram-Negative Bacteria
Iftikhar M. Ali
1
, Isam M. Ibrahim
1
, Entissar F. Ahmed
2
, Qayes A. Abbas
3
1
Department of Physics, College of Science, University of Baghdad, Baghdad, Iraq
2
Department of Biology, College of Science, University of Baghdad, Baghdad, Iraq
3
Department of Physics, College of Education for Pure Science, University of Anbar, Ramadi, Iraq
Received 9 October 2015; accepted 15 January 2016; published 18 January 2016
Copyright © 2016 by authors and Scientific Research Publishing Inc.
This work is licensed under the Creative Commons Attribution International License (CC BY).
http://creativecommons.org/licenses/by/4.0/
Abstract
The Manganese doped zinc sulfide nanoparticles of the cubic zinc blende structure with the aver-
age crystallite size of about 3.56 nm were synthesized using a coprecipitation method using Thio-
glycolic Acid as an external capping agent for surface modification. The ZnS:Mn
2+
nanoparticles of
diameter 3.56 nm were manufactured through using inexpensive precursors in an efficient and
eco-friendly way. X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Fourier Trans-
form Infrared (FTIR) spectroscopy are used to examine the structure, morphology and chemical
composition of the nanoparticles. The antimicrobial activity of (ZnS:Mn
2+
) nanocrystals was inves-
tigated by measuring the diameter of inhibition zone using well diffusion mechanism versus two
various bacterial strains. The technique of microorganism inactivation was considered as sorts-
dependent. Bacillus subtilis showed the largest antibacterial sensitivity (35 mm) to ZnS: Mn
2+
na-
noparticles at a concentration (50 mM) whereas Escherichia coli offered maximum zone of inhibi-
tion (20 mm) at the same concentration. In this study, the results indicated that ZnS:Mn
2+
nano-
particles were found to have significant antibacterial activity against Gram-negative (E. coli) and
Gram-positive (Bacillus subtilis) bacteria.
Keywords
Zinc Sulfide, Nanoparticles, Co-Precipitation Method, Antibacterial Activity