Journal of Water Resource and Protection, 2013, 5, 18-27
doi:10.4236/jwarp.2013.57A004 Published Online July 2013 (http://www.scirp.org/journal/jwarp)
A Study on Zeolite Performance in Waste Treating
Ponds for Treatment of Palm Oil Mill Effluent
M. Halim Shah Ismail
*
, Shazryenna Dalang, Syafiie Syam, Shamsul Izhar
Department of Chemical and Environmental Engineering, Faculty of Engineering,
Universiti Putra Malaysia, Serdang, Malaysia
Email:
*
mshalim@eng.upm.edu.my
Received April 27, 2013; revised May 29, 2013; accepted July 4, 2013
Copyright © 2013 M. Halim Shah Ismail et al. This is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
ABSTRACT
Oil palm currently occupies the largest acreage of farm land in Malaysia. In 2011, the production of palm oil in Malay-
sia was recorded as 19.8 million tons which has led to a huge amount of wastewater known as palm oil mill effluent
(POME). This work focuses on the ponding system which acts as wastewater treatment plant in order to treat POME.
The conventional ponding system applied in mills consists of a series of seven ponds. The maintenance costs of the
pond are expensive thus study of alternative methods is needed. POME treatment using zeolite shows a potential to
overcome the problem. Samples collected from selected ponds are tested and analyzed using water analyzer method.
Result from adsorption by zeolite shows a significant reduction of COD, BOD, Fe, Zn, Mn and turbidity. This shows
that zeolite is highly potential to be applied as adsorbent in the POME treatment plants. The results here may lead to
lower maintenance cost, lower quantity of treatment ponds and lesser land occupied for the treatment of POME in Ma-
laysia.
Keywords: Palm Oil Mill Effluent (POME); Zeolite; Wastewater Treatment
1. Introduction
Palm oil is one of the world’s most rapidly expanding
equatorial crops. Indonesia and Malaysia are the two
largest oil palm producing countries and is rich with nu-
merous endemic, forest-dwelling species. Malaysia has a
tropical climate and is prosperous in natural resources.
Oil palm currently occupies the largest acreage of farmed
land in Malaysia [1]. Over the recent years, there has
been a growing concern about the discharge of oil-con-
taining industrial wastewater into the ecosystem. Palm oil
processing in Malaysia annually produces a huge amount
of wastewater known as palm oil mill effluent (POME).
POME is a viscous brown liquid with fine suspended
solids at pH ranging between 4 and 5 [2]. Characteristics
of POME are tabulated in Table 1. In the process of
palm oil milling, POME is generated through steriliza-
tion of fresh oil palm fruit bunches, clarification of palm
oil and effluent from hydrocyclone operations [3]. It is
estimated that about 0.5 - 0.75 tons of POME are dis-
charged from the mill for every ton of fresh fruit bunch
(FFB) [4]. In Malaysia about 53 million m
3
POME is
being produced every year based on palm oil production
since 2005. Therefore, the challenge of converting POME
into an environmental friendly waste requires an efficient
treatment and effective disposal.
Ponding systems are easy operating systems but they
occupy a vast amount of land mass, relatively long hy-
draulic retention time (45 - 60 days) and bad odor. More-
over, it is difficult to maintain the liquor distribution and
biogas collection which leads to harmful effect on the
environment [5,6]. Another major disadvantage of using
ponding system is the formation of scum and solids that
tend to build up at the bottom of the pond. The sludge
and scum will clump together inside the pond lowering
the treatment efficiency. Therefore, the system requires
regular desludging process by either using submersible
pumps or excavators. Since the POME treatment applied
at mills consists of seven ponds, the maintenance cost for
all the ponds is very costly. Due to these facts, palm oil
mills face the challenge of balancing the environmental
protection, its economic viability and sustainable devel-
opment. There is an urgent necessity to find an approach
to preserve the environment while keeping the economy
growing.
*
Corresponding author.
Copyright © 2013 SciRes. JWARP