Climatic factors inuence leaf structure and thereby affect the ozone sensitivity of Ipomoea nil Scarlet O'Hara B arbara B. Moura * , Edenise S. Alves Instituto de Bot^ anica, Caixa Postal 3005, 01061-970 S~ ao Paulo, SP, Brazil article info Article history: Received 30 April 2014 Received in revised form 25 June 2014 Accepted 27 June 2014 Available online Keywords: Air pollution Bioindicator Tropical environment S~ ao Paulo Brazil abstract Phenotypic plasticity of the leaves can interfere with the plant sensitivity to ozone (O 3 ) toxic effect. This study aimed to assess whether the leaf structure of Ipomoea nil changes due to climatic variations and whether these changes affect the species' sensitivity. Field exposures, in different seasons (winter and spring) were made. The leaves that developed during the winter were thinner, with a lower proportion of photosynthetic tissues, higher proportion of intercellular spaces and lower density and stomatal index compared to those developed during the spring. The temperature and relative humidity positively inuenced the leaf thickness and stomatal index. The visible injuries during winter were positively correlated with the palisade parenchyma thickness and negatively correlated with the percentage of spongy parenchyma; during the spring, the symptoms were positively correlated with the stomatal density. In conclusion, the leaf structure of I. nil varied among the seasons, interfering in its sensitivity to O 3 . © 2014 Elsevier Ltd. All rights reserved. 1. Introduction The Metropolitan Region of S~ ao Paulo city (MRSP) is composed of 39 cities with a population of approximately 20 million habitants representing 75% of the population of S~ ao Paulo State. There are 8.5 million vehicles in this area, which contribute to high emission levels of primary pollutants in the air as a result of fuel combustion. As a result of complex photochemical reactions, ozone (O 3 ) is formed throughout the year in tropical environments (Moura et al., 2014b). O 3 is considered a powerful phytotoxic pollutant that can cause oxidative stress to vegetation, leading to the development of specic visible injury in the leaves due to reactive oxygen species (ROS), which react with lipids membranes (Schraudner et al., 1998), inducing a type of programmed cell death known as hypersensitive-like reaction (HR-like, Vollenweider et al., 2003; 2013; Moura et al., 2014a). An extended and integrated assessment of environmental in- dicators for global change is one of the most important emerging research eld (Serengil et al., 2011) and biomonitoring programs are an efcient alternative consistently for monitoring the levels of O 3 once the exposure is made following a standardized method during a time series using specic sensitive species (Klumpp et al., 2001). The intimate relation between the leaf structure and its physi- ological role has been discussed for a long time (Toth, 1982; Roderick et al., 1999). Within different populations of the same species, functional leaf traits may vary in relation to the extent that the plant succeeds in acclimating to ambient oxidative pressure (Bussotti, 2008). Higher palisade cell density and the greater spongy mesophyll intercellular space may result in a larger amount of free cell surface able to interact with O 3 (Bennet et al., 1992). Relatively large substomatal chambers and abundant intercellular spaces are anatomical features that reduce the resistance of leaves to gas exchange and therefore favor O 3 diffusion within the leaves (Calatayud et al., 2011). One of the most interesting endogenous differences that may lead to O 3 exposure sensitivity is stomatal density (Paoletti and Grulke, 2005). Stomatal distribution and behavior respond to a wide range of environmental stimuli such as light, humidity, and CO 2 (Paoletti and Grulke, 2005). Stomatal responses to air pollut- ants vary among species, leaf and tree age, and in conjunction with other environmental stressors (Manseld, 1998; Robinson et al., 1998). Differences in stomatal density can also be correlate with differences in the O 3 sensitivity of genotypes of the same species (Ferdinand et al., 2000). Ipomoea nil Scarlet O'Harais an O 3 -sensitive species (Nouchi and Aoki, 1979) that had been tested in tropical and subtropical environments (Moura et al., 2011; Ferreira et al., 2012). However, the efciency of I. nil Scarlet O'Harafor quantitative O 3 * Corresponding author. E-mail addresses: bmourabio@gmail.com, bmourabio@yahoo.com (B.B. Moura). Contents lists available at ScienceDirect Environmental Pollution journal homepage: www.elsevier.com/locate/envpol http://dx.doi.org/10.1016/j.envpol.2014.06.042 0269-7491/© 2014 Elsevier Ltd. All rights reserved. Environmental Pollution 194 (2014) 11e16