Biofabrication
Biofabrication 6 (2014) 035002 (12pp) doi:10.1088/1758-5082/6/3/035002
Usnic acid-loaded biocompatible magnetic
PLGA-PVA microsphere thin films
fabricated by MAPLE with increased
resistance to staphylococcal colonization
V Grumezescu
1,2
, A M Holban
3
, A M Grumezescu
1
, G Socol
2
, A Ficai
1
,
B S Vasile
1
, R Trusc˘ a
4
, C Bleotu
5
, V Lazar
3
, C M Chifiriuc
3
and G D Mogosanu
6
1
Department of Science and Engineering of Oxide Materials and Nanomaterials, Faculty of Applied
Chemistry and Materials Science, University Politehnica of Bucharest, Polizu Street no 1-7,
011061 Bucharest, Romania
2
Lasers Department, Plasma and Radiation Physics, National Institute for Lasers, PO Box MG-36,
Bucharest-Magurele, Romania
3
Microbiology Immunology Department, Faculty of Biology, University of Bucharest,
Aleea Portocalelor 1-3, Sector 5, 77206-Bucharest, Romania
4
Metav SA - CD SA, 31 Rosetti Str., 020015 Bucharest, Romania
5
Stefan S Nicolau Institute of Virology, Bucharest, Romania
6
Department of Pharmacognosy and Phytotherapy, Faculty of Pharmacy, University of Medicine and
Pharmacy of Craiova, 2 PetruRares ¸ Street, 200349 Craiova, Romania
E-mail: grumezescu@yahoo.com
Received 20 January 2014, revised 28 February 2014
Accepted for publication 10 March 2014
Published 11 April 2014
Abstract
Due to their persistence and resistance to the current therapeutic approaches, Staphylococcus
aureus biofilm-associated infections represent a major cause of morbidity and mortality in the
hospital environment. Since (+)-usnic acid (UA), a secondary lichen metabolite, possesses
antimicrobial activity against Gram-positive cocci, including S. aureus, the aim of this study
was to load magnetic polylactic-co-glycolic acid-polyvinyl alcohol (PLGA-PVA)
microspheres with UA, then to obtain thin coatings using matrix-assisted pulsed laser
evaporation and to quantitatively assess the capacity of the bio-nano-active modified surface to
control biofilm formation by S. aureus, using a culture-based assay. The UA-loaded
microspheres inhibited both the initial attachment of S. aureus to the coated surfaces, as well
as the development of mature biofilms. In vitro bioevalution tests performed on the fabricated
thin films revealed great biocompatibility, which may endorse them as competitive candidates
for the development of improved non-toxic surfaces resistant to S. aureus colonization and as
scaffolds for stem cell cultivation and tissue engineering.
Keywords: MAPLE, magnetic PLGA-PVA microspheres, biocompatibility, antibiofilm activity
(Some figures may appear in colour only in the online journal)
1. Introduction
Despite living in the era of antibiotics, microbial infections
represent one of the top public health problems at a
global level. Persistent infections, usually caused by resistant
pathogens with the ability to grow in biofilms, are very
frequent and difficult to treat due to their differing behavior
and increased susceptibility to antimicrobial agents [1] of
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