Nitrous oxide uxes from Malagasy agricultural soils L. Chapuis-Lardy a, , A. Metay a,b, 1 , M. Martinet b , M. Rabenarivo a , J. Toucet c , J.M. Douzet d , T. Razambelo e , L. Rabeharisoa e , J. Rakotoarisoa f a UR SeqBio IRD, c/o LRI, Université d Antananarivo, BP 434, 101 Antananarivo, Madagascar b ISTOM, 32 boulevard du Port, 95094 Cergy-Pontoise, Cedex 5, France c UR SeqBio IRD, ENSAM, 2 place Viala, bât. 12, 34060 Montpellier Cedex 2, France d URP SCRiD CIRAD c/o SRR FOFIFA B.P. 230, Antsirabe, Madagascar e LRI-SRA, Laboratoire des Radio-isotopes, Université d'Antananarivo, Route d'Andraisoro, BP 3383, 101 Antananarivo, Madagascar f URP SCRiD FOFIFA c/o SRR FOFIFA B.P. 230, Antsirabe, Madagascar abstract article info Article history: Received 17 April 2008 Received in revised form 11 September 2008 Accepted 14 November 2008 Available online 6 December 2008 Keywords: Tropical soil No-tillage N 2 O emissions Soil mineral N WFPS IPCC N 2 O emission factor In Madagascar, no-tillage practices were developed since the early 90s to prevent soil erosion and improve soil fertility. Although such practices have helped to restore soil carbon in most cases, the impact on N 2 O emissions has not been investigated yet. The soil N 2 O uxes and concentrations were measured during the growing season of an intercropping maize-soybean on a clayey soil of the Malagasy Highlands. Management treatments consisted of direct seeding mulch based cropping system (DMC) and traditional hand-ploughing after the preceding crop residues were harvested (HP), both with low N inputs (5557 kg N ha - 1 ). No signicant difference in N 2 O emissions was observed between treatments (DMC vs. HP). The N 2 O uxes were weakly correlated to soil mineral N contents (R 2 = 0.13; P = 0.03) while no relationship was emphasized with soil water lled pore space (WFPS). N 2 O concentrations in the soil atmosphere were correlated to uxes at the soil surface and to soil WFPS. N 2 O emissions at the soil surface were low ranging from 0 to 8.84 g N-N 2 O ha - 1 d - 1 , probably due to the low mineral N content of soil. The cumulative annual N 2 O emission was 0.26 kg N ha - 1 for both systems. The corresponding N loss as N 2 O-N was around 0.5% of applied N. This is in the uncertainty range of IPCC N 2 O emission factor (EF), but the IPCC EF mean estimate (1%) would overestimate true N 2 O emissions for the soil under evaluation. © 2008 Elsevier B.V. All rights reserved. 1. Introduction In the last few centuries, human activities such as industry, trans- port and agriculture have directly or indirectly contributed to the increase in concentrations of the major greenhouse gases in the at- mosphere (Intergovernmental Panel on Climate Change, 2001). Three of the principal gases of interest are nitrous oxide (N 2 O), carbon dioxide (CO 2 ) and methane (CH 4 ). Both N 2 O and CO 2 are emitted from the soil, whereas CH 4 is normally oxidized by aerobic soils, making them sinks for atmospheric CH 4 (Hütsch, 2001). Agricultural soils contribute about 60% of the global anthropogenic N 2 O ux, which is equivalent to a global warming potential of 2.8 Gt CO 2 eq yr - 1 (In- tergovernmental Panel on Climate Change, 2007). N 2 O is produced during numerous nitrogen transformations in soils (Robertson and Tiedje, 1987), but on most occasions denitrication and nitrication are the main sources. A synthesis of results on N oxide (N 2 O+NO) uxes from natural or unfertilized systems in the humid tropics indicates that the uxes are positively correlated with some measure of N availability (soil inorganic N) and with soil water-lled pore space (WFPS) (Granli and Bøckman, 1995; Verchot et al., 1999; Davidson et al., 2000). Theory suggests that the relationship between N inputs and N 2 O ux may be more complex, and in particular that N 2 O ux may exhibit a threshold response to N inputs and soil biota (Erickson et al., 2001). Nitrogen often limits both plant growth and N 2 O production in terrestrial ecosystems, so that where plants are competing with microbes for soil N, N 2 O production will be suppressed until plant N demands have been fully satised. The IPCC protocols calculate agriculture's contribution to atmospheric N 2 O loading as a simple percentage of total N inputs: 1% of added N is estimated to be lost as N 2 O based on uxes from fertilized vs. unfertilized eld plots (Intergovernmental Panel on Climate Change, 2006). While fertilization rate may be low in tropical countries, responses of N 2 O uxes to low levels of N inputs are unknown for many tropical soils. The number of published measurements of N 2 O emissions from soils is increasing steadily at mid-latitudes (Europe and North America) but there are still few ux data from tropical and sub-tropical regions (Bouwman et al., 2002; Stehfest and Bouwman, 2006). The representation of tropical Geoderma 148 (2009) 421427 Corresponding author. E-mail address: lydie.lardy@ird.fr (L. Chapuis-Lardy). 1 Current afliation: SupAgro, UMR SYSTEM (INRA-CIRAD-SupAgro), 2 place Viala, Bât. 27, 34060 Montpellier Cedex 2, France. 0016-7061/$ see front matter © 2008 Elsevier B.V. All rights reserved. doi:10.1016/j.geoderma.2008.11.015 Contents lists available at ScienceDirect Geoderma journal homepage: www.elsevier.com/locate/geoderma