1070
ISSN 1028-334X, Doklady Earth Sciences, 2006, Vol. 410, No. 7, pp. 1070–1074. © Pleiades Publishing, Inc., 2006.
Original Russian Text © V.A. Lebedev, I.V. Chernyshev, A.S. Avdeenko, A.A. Nosova, A.Ya. Dokuchaev, T.I. Oleinikova, Yu.V. Gol’tsman, 2006, published in Doklady Akademii
Nauk, 2006, Vol. 410, No. 1, pp. 95–100.
Late Miocene subalkaline granite magmatism in the
Caucasian Mineral Waters (CMW) region is related to
the first stage of Late Cenozoic magmatic activity in the
Caucasian segment of the Alpine foldbelt. The young
age and presence of uranium mineralization, as well as
other factors including easy availability, promoted
detailed study of these intrusions in geological [1, 2],
mineralogical, petrographical, geochemical, and physi-
cochemical aspects [3–7]. The CMW region known as
Mineral’nye Vody (Fig. 1) is confined to the ring struc-
ture in the northern termination of Transcaucasus
Transverse Uplift. The intrusions typically form stocks
with deep subvertical contacts, and their exposures are
no more than 5 km
2
in area. The presence of granite
pebbles at the base of Late Miocene sedimentary
sequence unambiguously indicates the Post Paleogene
age of the subalkaline magmatism in the region.
The massifs are made up of leucogranite–granite
and alkaline granite–granosyenite–syenite series [1, 7].
The granitoids typically exhibit porphyritic texture and
consist of phenocrysts and fine-grained groundmass.
Syenites and granosyenites contain phenocrysts of
sanidine, plagioclase, phlogopite, and clinopyroxene.
In granites which also contain quartz, clinopyroxene is
replaced by hornblende. Phenocrysts in leucogranites
occur as quartz and feldspars. In terms of geochemical
characteristics, subalkaline rocks of the CMW region
are classified as latite (shoshonite) granites typical of
late collisional and postcollisional stages of the evolu-
tion of foldbelts [7]. The geology, composition, and
crystallization conditions of granitoids of the CMW
region are considered in detail in [1, 7].
The problem of age and chronology of CMW gran-
itoid massifs remains debatable. Available K–Ar and
39
Ar–
40
Ar datings do not always coincide and span only
part of the known massifs. Of special interest is their
formation history, especially in view of the recognition
of two or even three phases for some massifs in petro-
logical works [1, 7].
The first K–Ar determinations were performed
30 years ago and ranged within 10.5–8 Ma [3, 8] which
unambiguously confirmed their Late Miocene age pre-
viously inferred from geological data. In later studies,
the granites were dated by analytically improved K–Ar
method at the Institute of Geology of Ore Deposits,
Petrography, Mineralogy, and Geochemistry (Moscow)
[9] and for the first time by the
39
Ar–
40
Ar method at
Heidelberg University [5, 6].
K–Ar datings on five phlogopite samples from the
Kinzhal, Sheludivaya, Ostraya, Zmeika, and Verblyud
massifs are reported in [9]. Three datings are within
8.40–8.25 Ma, while two others fall around 9.3 Ma. No
correlation was found between the age and composition
of the rocks, while K–Ar data were interpreted as the
uplift time, i.e., exhumation of the host crustal blocks
above the 300°C isograd. These authors believed that
the intrusions are slightly older than 9 Ma. Based on our
more detailed K–Ar data, we shall show that the appar-
ent different ages of the CMW massifs noted in [9] can
be interpreted in a different way.
An incremental step heating
39
Ar–
40
Ar method was
applied by Hess, Paul, and others to date these massifs
[5, 6]. They studied three sanidine–phlogopite mineral
pairs from rocks of the Razvalka, Kinzhal, and Zmeika
massifs and two sanidine samples from rocks of the
Ostraya and Zolotoi Kurgan massifs. All dated samples
define plateau age spectra, indicating rapid cooling and
subsequent closure of the K–Ar isotope mineral sys-
tem. The obtained data are plotted in a narrow range of
8.4–8.1 Ma, which allowed the authors to conclude that
the age of CMW massifs is ~8.25 Ma. It should be
Heterogeneity of Ar and Sr Initial Isotopic Composition
in the Coexisting Minerals from Miocene Hypabyssal Granitoids
in the Caucasian Mineral Waters Region
V. A. Lebedev, Corresponding Member of the RAS I. V. Chernyshev, A. S. Avdeenko,
A. A. Nosova, A. Ya. Dokuchaev, T. I. Oleinikova, and Yu. V. Gol’tsman
Received April 6, 2006
DOI: 10.1134/S1028334X06070154
Institute of Geology of Ore Deposits, Petrography,
Mineralogy, and Geochemistry, Russian Academy of
Sciences, Staromonetnyi per. 35, Moscow, 119017 Russia
e-mail: leb@igem.ru
GEOCHEMISTRY