Materials Sciences and Applications, 2015, 6, 1061-1070
Published Online November 2015 in SciRes. http://www.scirp.org/journal/msa
http://dx.doi.org/10.4236/msa.2015.611105
How to cite this paper: Al-Saadie, K.A., Abas, H.A. and Almashhdani, H.A.Y. (2015) Corrosion Protection of Iron Alloy Using
Peganum harmala Extract as Inhibitor in Acidic Solution. Materials Sciences and Applications, 6, 1061-1070.
http://dx.doi.org/10.4236/msa.2015.611105
Corrosion Protection of Iron Alloy Using
Peganum harmala Extract as Inhibitor in
Acidic Solution
Khulood Abid Al-Saadie
1*
, Hayfaa Ameer Abas
1
, Haider Abdulkareem Yousif Almashhdani
2
1
Department of Chemistry, College of Science, Baghdad University, Baghdad, Iraq
2
Department of Dentistry, Al-Rasheed University College, Baghdad, Iraq
Received 18 October 2015; accepted 24 November 2015; published 27 November 2015
Copyright © 2015 by authors and Scientific Research Publishing Inc.
This work is licensed under the Creative Commons Attribution International License (CC BY).
http://creativecommons.org/licenses/by/4.0/
Abstract
This work describes the inhibition effect of different concentration of an aqueous extracted of Pe-
ganum harmala seed on the corrosion of carbon steel in 1 M H2SO4 solution using potentiostatic
polarization techniques at the temperature range (298 - 328) K. The result showed that the inhibi-
tion efficiency increased with increasing of extract inhibitor concentration and temperature. The
adsorption of inhibitor on carbon steel surface was fit into Langmuir adsorption isotherm. Kinetic
and thermodynamic parameters governing the corrosion and the adsorption process were calcu-
lated and discussed.
Keywords
Corrosion, Carbon Steel, Seed, Peganum harmala, Acidic Solution
1. Introduction
Corrosion is recognized as the number one life limiting plant degradation mechanism [1] and exhibited by most
engineering materials in nearly all environments [2]. There are numerous methods for controlling the corrosion
of metals but the use of inhibitors is still one of the best methods of protecting metals against corrosion. Many
organic compounds are used as corrosion inhibitors for metals in acidic environments [3]. Corrosion inhibitors
are substance that when adsorbed onto the metal-solution interface, blocks the corrosive material from coming
into contact with metal. A number of heterocyclic compounds containing nitrogen, oxygen and sulphur either in
the aromatic or in long chain carbon system have been reported to be effective inhibitors [4]. Extracts of various
*
Corresponding author.