PHYSICAL REVIEW E 90, 042504 (2014)
Optics of short-pitch deformed-helix ferroelectric liquid crystals: Symmetries, exceptional points,
and polarization-resolved angular patterns
Alexei D. Kiselev
1, 2, *
and Vladimir G. Chigrinov
1 , †
1
Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong
2
Institute of Physics of National Academy of Sciences of Ukraine, prospekt Nauki 46, 03680 Kiev, Ukraine
(Received 13 July 2014; published 24 October 2014)
In order to explore electric-field-induced transformations of polarization singularities in the polarization-
resolved angular (conoscopic) patterns emerging after deformed-helix ferroelectric liquid crystal (DHFLC) cells
with subwavelength helix pitch, we combine the transfer matrix formalism with the results for the effective
dielectric tensor of biaxial FLCs evaluated using an improved technique of averaging over distorted helical
structures. Within the framework of the transfer matrix method, we deduce a number of symmetry relations and
show that the symmetry axis of L lines (curves of linear polarization) is directed along the major in-plane optical
axis which rotates under the action of the electric field. When the angle between this axis and the polarization
plane of incident linearly polarized light is above its critical value, the C points (points of circular polarization)
appear in the form of symmetrically arranged chains of densely packed star-monstar pairs. We also emphasize
the role of phase singularities of a different kind and discuss the enhanced electro-optic response of DHFLCs
near the exceptional point where the condition of zero-field isotropy is fulfilled.
DOI: 10.1103/PhysRevE.90.042504 PACS number(s): 61.30.Gd, 78.20.Jq, 77.84.Nh, 42.70.Df
I. INTRODUCTION
Over the last more than three decades, ferroelectric liq-
uid crystals (FLCs) have attracted considerable attention as
promising chiral liquid crystal materials for applications in fast
switching display devices (a detailed description of FLCs can
be found, e.g., in monographs [1,2]). Equilibrium orientational
structures in FLCs are represented by helical twisting patterns
where FLC molecules align on average along a local unit
director
ˆ
d = cos θ
ˆ
h + sin θ ˆ c, (1)
where θ is the smectic tilt angle,
ˆ
h is the twisting axis normal
to the smectic layers, and ˆ c ⊥
ˆ
h is the c director. The FLC
director (1) lies on the smectic cone depicted in Fig. 1(a) with
the smectic tilt angle θ and rotates in a helical fashion about a
uniform twisting axis
ˆ
h forming the FLC helix with the helix
pitch P . This rotation is described by the azimuthal angle
around the cone that specifies orientation of the c director in
the plane perpendicular to
ˆ
h and depends on the dimensionless
coordinate along the twisting axis
φ = 2π (
ˆ
h · r)/P = qx, (2)
where q = 2π/P is the helix twist wave number.
The important case of a uniform lying FLC helix in the slab
geometry with the smectic layers normal to the substrates and
ˆ
h = ˆ x, ˆ c = cos ˆ y + sin ˆ z, E = E ˆ z, (3)
where E is the electric field applied across the cell, is illustrated
in Fig. 1. This is the geometry of surface stabilized FLCs
(SSFLCs) pioneered by Clark and Lagerwall in Ref. [3].
They studied electro-optic response of FLC cells confined
between two parallel plates subject to homogeneous boundary
*
kiselev@iop.kiev.ua
†
eechigr@ust.hk
conditions and made thin enough to suppress the bulk FLC
helix.
It was found that such cells exhibit high-speed, bistable
electro-optical switching between orientational states stabi-
lized by surface interactions. The response of FLCs to an
applied electric field E is characterized by fast switching times
due to linear coupling between the field and the spontaneous
ferroelectric polarization
P
s
= P
s
ˆ p, ˆ p =
ˆ
h × ˆ c = cos ˆ z − sin ˆ y, (4)
where ˆ p is the polarization unit vector. There is also a threshold
voltage necessary for switching to occur and the process of
bistable switching is typically accompanied by a hysteresis.
Figure 1(b) also describes the geometry of deformed-helix
FLCs (DHFLCs) as it was introduced in Ref. [4]. This case
will be of our primary concern.
In DHFLC cells, the FLC helix is characterized by a short
submicron helix pitch P< 1 μm, and a relatively large tilt
angle θ> 30
◦
. By contrast to SSFLC cells, where the surface
induced unwinding of the bulk helix requires the helix pitch of
a FLC mixture to be greater than the cell thickness, a DHFLC
helix pitch is 5–10 times smaller than the thickness. This allows
the helix to be retained within the cell boundaries.
Electro-optical response of DHFLC cells exhibits a number
of peculiarities that make them useful for LC devices such
as high-speed spatial light modulators [5–9], color-sequential
liquid crystal display cells [10], and optic fiber sensors [11].
The effects caused by electric-field-induced distortions of the
helical structure underline the mode of operation of such cells.
In a typical experimental setup, these effects are probed by
performing measurements of the transmittance of normally
incident linearly polarized light through a cell placed between
crossed polarizers.
A more general case of oblique incidence has not received
a fair amount of attention. Theoretically, a powerful tool to
deal with this case is the transfer matrix method which has
been widely used in studies of both quantum mechanical and
1539-3755/2014/90(4)/042504(19) 042504-1 ©2014 American Physical Society