PHYSICAL REVIEW A 86, 052706 (2012)
Electron excitation of the 4
1
P
1
state of a zinc atom
Mariusz Piwi´ nski,
*
Lukasz Klosowski, Dariusz Dziczek, and Stanislaw Chwirot
Nicolaus Copernicus University, Institute of Physics, Grudzia ˛dzka 5/7, 87-100 Toru´ n, Poland
Tapasi Das and Rajesh Srivastava
Department of Physics, Indian Institute of Technology, Roorkee 247 667 Uttranchal, India
A. D. Stauffer
Department of Physics and Astronomy, York University, Toronto, Ontario, Canada M3J 1P3
Christopher J. Bostock, Dmitry V. Fursa, and Igor Bray
ARC Centre for Antimatter-Matter Studies, Curtin University, GPO Box U1987, Perth, Western Australia 6845, Australia
(Received 27 September 2012; published 19 November 2012)
Experimental results of Stokes parameters and electron-impact coherence parameters for excitation of
4
1
P
1
state of zinc atoms are presented. The electron-photon coincidence method in the coherence-analysis
version was applied to obtain data for scattering angles in the range from 5
◦
to 40
◦
for incident electron
energy 100 eV. The experimental results are presented together with convergent-close-coupling-method and
relativistic-distorted-wave-approximation theoretical predictions.
DOI: 10.1103/PhysRevA.86.052706 PACS number(s): 34.80.Dp, 34.80.Pa
I. INTRODUCTION
Alkaline-earth metals and other atoms with two valence
electrons outside a relatively inert core such as Zn, Ca, Cd, and
Hg are very interesting objects for theoretical and experimental
investigations of electronic collisions.
The most detailed information about inelastic-scattering
processes can be obtained in electron-photon coincidence
measurements [e.g., Stokes parameters or electron-impact
coherence parameters (EICPs)]. Due to the complexity and
long time required for such experiments, the amount of
available data on such collision systems is rather limited
[1–11]. Therefore, more experimental results are still needed
to test and develop the theoretical models.
The present work is a continuation of our previous
coincidence studies of electron scattering on Ca and Cd
atoms [12–14]. The next target—zinc—has been investigated
in experimental and theoretical studies of interactions with
polarized electrons. Very interesting information on spin-
dependent effects in formation of negative ions has been
summarized in Ref. [15]. Some unexpected effects have been
also revealed in
3
S
1
state excitation by polarized electrons [16],
providing additional justification for coincidence experiments
on Zn. The first set of coherence parameters for Zn atoms
excited to the 4
1
P
1
state by electrons with incident energy of
100 eV is presented in this paper. The theoretical relativistic-
distorted-wave approximation (RDWA) and convergent-close-
coupling (CCC) predictions for the full range of scattering
angles are also shown.
II. APPARATUS
The experimental setup used in the present work was
essentially the same as the one used in experiments on
*
Mariusz.Piwinski@fizyka.umk.pl
electron-impact excitation of cadmium atoms [14,17]. A
diagram of the apparatus is shown in Fig. 1. The geometry of
the experiment was typical for the coherence-analysis version
of electron-photon coincidence measurements.
The electron-atom collisions took place in a vacuum
chamber with typical pressure of 5 × 10
−7
mbar with the Zn
atomic beam effusing from a magnetically shielded oven.
The electron and atomic beams were cross-fired, creating an
interaction region of a diameter 1.5–2 mm located 22 mm
above the two-stage collimator of the atom source. The typical
operating temperatures of the oven were 341
◦
C for the main
reservoir and 355
◦
C for the nozzle. Number density of the Zn
atoms was of the order of 10
10
atoms/cm
3
in the interaction
region. The electron beam of energy 100 eV and 3–6 μA of
current was produced by a Comstock EG-402EL electron gun.
A Comstock AC-901 electrostatic electron-energy analyzer
was used for energy selection of the electrons scattered by
atoms and observed at the fixed scattering angle .
During coincidence measurements the analyzer transmitted
electrons which had lost the energy corresponding to the
excitation of Zn atoms from their ground to the 4
1
P
1
state.
The combined energy resolution of the electron gun and
the energy analyzer was about 0.7 eV. The acceptance angle
of the electron detection channel was 0.06 rad. A typical
energy-loss spectrum is shown in Fig. 2.
Photons of the wavelength 213.8 nm emitted spontaneously
by atoms relaxing from the 4
1
P
1
to their ground state were
detected in the direction perpendicular to the scattering plane
defined by the momenta of the impacting and the observed
scattered electrons. The polarization state of the emitted
radiation was determined with a custom-made pile-of-plates
polarizer and a zero-order quartz retardation plate (Melles
Griot). The acceptance angle of the photon detection channel
was approximately 0.2 rad.
The coincidence circuitry used in the experiment was the
same as in the previous experiments on cadmium atoms [14]. A
typical accumulated coincidence spectrum is shown in Fig. 3.
052706-1 1050-2947/2012/86(5)/052706(5) ©2012 American Physical Society