IOP PUBLISHING NANOTECHNOLOGY
Nanotechnology 20 (2009) 465709 (7pp) doi:10.1088/0957-4484/20/46/465709
Ideal strength on clusters from first
principles: the Ti
13
case
M Salazar Villanueva
1,2,3
, A H Romero
1,3
and
A Bautista Hern´ andez
2
1
Cinvestav, Unidad Quer´ etaro, Libramiento Norponiente 2000, Real de Juriquilla, CP 7230,
Quer´ etaro, Mexico
2
Facultad de Ingenier´ ıa, Universidad Aut´ onoma de Puebla, Apartado Postal J-39, CP 72570,
Puebla, Mexico
E-mail: martin.salazar@fi.buap.mx and aromero@qro.cinvestav.mx
Received 6 March 2009, in final form 9 September 2009
Published 22 October 2009
Online at stacks.iop.org/Nano/20/465709
Abstract
The mechanical behavior of a Ti
13
cluster, based on total energy mechanical quantum
calculations is studied. The cluster geometry has been optimized and good agreement with
previous reports has been found. Axial strain is applied along one of the principal axes and the
changes on the energetic and vibrational properties of the system are followed. To characterize
the cluster stability as a function of strain, vibrational frequencies and total energy have been
calculated, to obtain the cluster maximum load tolerance for compression (C ) and tensile (T ).
If the maximum load is defined through a vibrational instability, it happens to be two and half,
and three times larger than when the maximum total energy is considered (C and T
respectively). As a result of the induced strain along of the C
5
symmetry element, the cluster
changes its point group symmetry from I
h
to D
5d
, with an energy difference of 1.17 eV (for
compression) and 0.33 eV (for tension) with respect to the ground state geometry. The
electronic changes are also characterized, as function of the strain, by following the
modifications of the highest occupied molecular orbital (HOMO), the lowest unoccupied
molecular orbital (LUMO) and changes on the total atomic population.
1. Introduction
Small titanium clusters have attracted the attention of
theoreticians and experimentalists in the last few years, mainly
because they have shown a large potential in nanotechnology.
Namely, in applications such as pigment fabrication, used
to characterize corrosion, hydrogen storage, photocatalyzers
and solar cells [1–11], most of those properties are system
and structurally dependent and it is necessary to see their
effect in the final product. Between the many interesting
cluster structural properties, one exhibited by titanium is the
so called formation of magic numbers [12], which is a unique
relation between, stability, geometrical symmetry and atomic
number. This relation has been observed in experiments [16]
as well as in theoretical studies [13–15]. The first magic
numbers in small titanium clusters correspond to 7, 13 and
15 atoms [12, 16]. For example, a complete structural and
electronic characterization, as a function of the atomic number,
has been reported in [13–15, 17]. Much more recently,
3
Authors to whom any correspondence should be addressed.
researchers have directed their attention to the modification of
the electronic and structural properties of these finite systems
by application of external fields, such as pressure, temperature,
electromagnetic fields, etc. Recently Krauss et al [18] have
studied the compressibility of silver (10 nm) and gold (30 nm)
nanoparticles and found an unexpected behavior as a function
of size. Principally, they found that nanoparticles have
a significantly higher stiffness than the corresponding bulk
materials. The results of these experiments have motivated
theoretical studies of mechanical properties of small molecular
nano-structured components such as nano-films, nano-wires
(tubes and cylinders) and nano-dots (clusters) [19–27]. Just as
in crystalline systems [28], the ideal strength in clusters could
be defined as the energy inflexion point in an energy versus
strain curve, which corresponds to a maximum in the load–
strain diagram. The dependence of the mechanical response
is also controlled by the vibrational instabilities and they need
to be also considered within a mechanical study of any given
system. Therefore, in order to have a unique definition of the
ideal strength for finite systems, inclusion of the vibrations as
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