0011-9164/09/$– See front matter © 2009 Elsevier B.V.
Desalination 239 (2009) 334–345
Chemical stability of inline blends of desalinated, surface and
ground waters: the need for higher alkalinity values in
desalinated water
Ori Lahav
a*
, Elad Salomons
b
, Avi Ostfeld
a
a
Faculty of Civil and Environmental Engineering, Technion–Israel Institute of Technology, Haifa 32000, Israel
Tel. +972 (4) 829-2191; Fax: +972 (4) 822-8898; email: agori@tx.technion.ac.il
b
OptiWater, 6 Amikam Israel Street, Haifa 34385, Israel
Received 11 May 2008; Accepted 20 July 2008
Abstract
Blending desalinated water with surface and/or ground water may result in water that has a negative precipitation
potential with respect to CaCO
3(s)
, rendering it chemically unstable. In this paper a simulation tool for calculating the
pH and calcium carbonate precipitation potential (CCPP) values at the nodes of a water distribution system is
introduced. This computerized tool is then used to simulate the CCPP values that would develop in a schematic
distribution system fed by three water sources (desalinated, surface and ground waters) under a simulative water
consumption pattern. The simulation demonstrates, for a case study that is based on typical Israeli conditions, that
an increase in the alkalinity value of the desalinated water from 50 to 100 mg/L as CaCO
3
results in a positive CCPP
value at all times whereas at the low alkalinity value (which is the concentration which is currently supplied by the
100 million-m
3
/y and 30 million-m
3
/y Ashkelon and Palmachim plants in Israel) the CCPP values at the nodes are
often negative as a result of blending the desalinated water with groundwater. The conclusion is that there is a need
to increase the alkalinity value in desalinated waters. This request is augmented by additional arguments in support
of this approach. The negative effect of high alkalinity values on copper-tubing corrosion rates is also noted.
Keywords: Alkalinity; CCPP; Simulation tool; Distribution systems; Pipe corrosion
1. Introduction
Desalinated water is providing an increasing
portion of the total fresh water supply in a
*Corresponding author.
growing number of countries. The global desali-
nation market is presently estimated at around
8 billion m
3
annually, and since global water
consumption is predicted to double itself every
20 years, this number is expected to increase
doi:10.1016/j.desal.2008.07.006
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