Synthetic Metals, 41-43 (1991) 2119-2122 2119
TEMPERATURE DEPENDENT HALL COEFFICIENT OF THE ORGANIC SUPERCONDUCTOR
~-DI(BIS(ETRYLENEDITHIOLO)TETRATHIAFULVALENE)TRIIODIDE, ~-(BEDT-TTF)2I 3
B.Korin-Hamzid, L.ForrO and J.R.Cooper
Institute of Physics of the University, POB 304, 41000 Zagreb, Yugoslavia
ABSTRACT
We report Hall effect data (R H) for two single crystals of the organic
superconductor E-(BEDT-TTF)213 in the low Tc phase (EL). An unexpected
temperature dependence is obtained with a broad maximum in R H near 40K. A
possible interpretation in terms of electron-electron scattering is discussed.
INTRODUCTION
The organic superconductor E-(BEDT-TTF)213, shows several interesting
properties [13: it has a low (EL) and high (EH) T c superconducting phases with
T = 1.2K and 8K respectively, unusual structural phase transitions and
c
displays Shubnikov de Haas oscillations in high magnetic fields [23. The
understanding of some basic properties is still incomplete.
Hall measurements are less common for organic conductors because the
crystals are small and there are difficulties in making proper noise-free
contacts. The common feature of the available data in quasi one- dimensional
conductors (i.e.two chain systems) e.g. TTF-TCNQ [3J and HMTSF-TCNQ ~4]is that
RH is temperature dependent in the metallic phase, much above the
transitions to a Peierls semiconductor or to a semimetallic state. This
behaviour was attributed by M.Weger [3~ to a dimensional crossover i.e. to a
diffusive-coherent transition between the chains. Although E-(BEDT-TTF)213 is
a single chain system it is unusual in that it has less conductivity
anisotropy, than the Bechgaard salts, and there is probably no
diffusive-coherent transition in the ab plane. Indeed Bulaevskii has
convincingly argued that at all temperatures the conductivity is dominated by
electron-electron Umklapp scattering over a closed FS [1].
The Hall data reported here do show considerable temperature dependence.
The results and discussion in more details are published in ref.5. Independent
study of DC Hall effect of the low T c (EL) state is published in ref.6.
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