Energy 29 (2004) 1599–1609 www.elsevier.com/locate/energy Geologic storage of CO 2 from refining and chemical facilities in the midwestern US Neeraj Gupta a,Ã , Bruce Sass a , Sandip Chattopadhyay a , Joel Sminchak a , Peng Wang b , Tony Espie c a Environmental Restoration Department, Battelle Memorial Institute, 505 King Avenue, Columbus, OH 43201-2693, USA b DeGolyer and MacNaughton, 4925 Greenville Avenue, Dallas, TX 75206, USA c BP, Reservoir Management Team, Chertsey Road, Sunbury-on-Thames, Middlesex TW16 7LN, UK Abstract Three locations in the midwestern US were evaluated for saline reservoir sequestration of CO 2 transported from refineries and chemical plants along existing pipeline rights-of-way. Based on formation volume calculations, the potential storage capacity in a single formation (the Mt. Simon Sandstone) is in the range of several billion tons. Compositional reservoir simulations using single-well radial models were completed to predict the formation pressures, CO 2 spreading, and dissolution following injection. Injectivity at all sites appears to be sufficient for more than 1 Mt/year/well of CO 2 without exceeding the fracture pressure limits, and no leakage of CO 2 into shallower horizons was predicted. A horizontal injec- tion well scenario showed a smaller increase in reservoir pressure than vertical wells. The geochemical evaluation included a summary of the brine chemistry and mineralogy of the reservoir and caprock for- mations. Equilibrium geochemical simulations for several scenarios did not indicate any adverse reactions as a result of CO 2 injection. A preliminary economic and engineering assessment of several injection scenarios showed that the cost of CO 2 dehydration, compression, transport, and injec- tion is nearly $ 20/t, excluding capture costs. The largest capital cost is compression and pipeline systems, and the largest operational cost is compression. System costs may be reduced by optimizing the location of storage reservoirs closer to the emission sources or through development of a regional shared transport network and storage site. # 2004 Elsevier Ltd. All rights reserved. Ã Corresponding author. Tel.: +1-614-424-3820; fax: +1-614-424-3667. E-mail address: gupta@battelle.org (N. Gupta). 0360-5442/$ - see front matter # 2004 Elsevier Ltd. All rights reserved. doi:10.1016/j.energy.2004.03.062