CALPHAD: Computer Coupling of Phase Diagrams and Thermochemistry 37 (2012) 87–93
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CALPHAD: Computer Coupling of Phase Diagrams and
Thermochemistry
journal homepage: www.elsevier.com/locate/calphad
Thermodynamic assessment of Au–Ho and Au–Tm binary systems
H.Q. Dong
a,*
, X.M. Tao
b
, T. Laurila
a
, M. Paulasto-Kröckel
a
a
Department of Electronics, School of Electrical Engineering, Aalto University, FIN-02601 Espoo, Finland
b
Key Laboratory of New Processing Technology for Nonferrous Metals and Materials of Ministry of Education, College of Physical Science and Technology, Nanning 530004, PR China
article info
Article history:
Received 2 November 2011
Received in revised form
7 February 2012
Accepted 8 February 2012
Available online 8 March 2012
Keywords:
Au–Ho
Au–Tm
CALPHAD
Thermodynamic assessment
ab initio calculations
abstract
Phase relationships in Au–Ho and Au–Tm binary systems have been thermodynamically assessed by using
the CALPHAD technique. The existing thermodynamic descriptions of the systems were improved by
incorporating the ab initio calculated enthalpies of formation of the intermetallic compounds (IMCs) to
the assessment. All the binary intermetallic compounds were treated as stoichiometric phases, while
the solution phases, including liquid, fcc, and hcp, were treated as substitutional solution phases.
Furthermore, the excess Gibbs energies were formulated with the Redlich–Kister polynomial function. As
a result, two self-consist thermodynamic data sets for describing the Au–Ho and Au–Tm binary systems
have been obtained.
© 2012 Elsevier Ltd. All rights reserved.
1. Introduction
Bonding dissimilar materials is one of the essential steps in
the fabrication of modern electronic devices. Prominent examples
are integrated circuit (IC) and Micro-Electro-Mechanical Systems
(MEMS) devices packaging. Typically, the reliability of MEMS
devices packaging at the wafer-level depends on the bonding
systems to a large extent. There are two primary types of
generally used bonding technologies, namely, ‘‘dielectric bonding’’
and ‘‘metallic bonding’’ [1,2]. The latter one has distinguished
advantages coming from the metal layer, which can add further
functionality to a final 3D IC and MEMS devices, as the metal layer
provides not only mechanical but also an electrical and a thermal
connection [1,3]. Therefore, it is of utmost importance to obtain
a better understanding of the thermodynamics of the related
metallic bonding systems. The knowledge about the formation of
intermetallic compounds is particularly important.
It is well established that gold, as an element, has many favor-
able physical and chemical properties (i.e. good thermal and elec-
trical conductivity, excellent corrosion resistance). Consequently,
Au and Au metallizations are widely applied as a surface finish with
traditional solder materials, as the wire or the pad metal in wire
bonding and as the base metal in wafer-level bonding, examples
including such systems are Au–Sn and Au–In [4–7].
Rare earth (RE) metals, which can react with almost all the
elements in the periodic table, have increasingly been used in
*
Corresponding author.
E-mail address: hongqun.dong@aalto.fi (H.Q. Dong).
MEMS packaging in order to promote bonding [8–10]. For this
purpose, RE metals can be used as an alloying elements in Au–Sn-
based and Sn–Ag-based solders. This, however, requires that there
is sufficient solubility of the RE elements to the solder base
metals used. In some cases RE materials are used as one of the
bonding layers between two wafers, two chips or wafer/chip,
in order to provide a hermetic, conductive bond with small
dimensions [11].
Hence, to utilize the full technological potential of the RE ele-
ments, it is essential to have a fundamental knowledge about the
Au–RE systems, such as information about the phase equilibrium
and the related thermodynamic data. Unfortunately, the phase di-
agrams for Au–RE have not been systematically investigated, with
the notable exceptions of the thermodynamic assessment of the
Au–X
1
(X
1
= Pr, La and Er) [12,13] and the experimentally inves-
tigated Au–X
2
systems (X
2
= Tm, Gd, Ho, Er and Tm) [14,15]. Both
Ho and Tm exhibit solid state solubility to Au (fcc) phase (about 5
at%) thus making them potential candidates as alloying elements in
Au-based solders. Since there also exists an experimentally mea-
sured phase diagram with Au for both of the elements [14], they
were chosen for closer investigation. Thus, the thermodynamic as-
sessment of the Au–Ho and the Au–Tm binary systems are carried
out in this work by combining ab initio techniques [16,17] with the
CALPHAD approach [18]. Two self-consistent thermodynamic data
sets were obtained for the Au–Ho and the Au–Tm systems, respec-
tively. The paper is organized as follows: a brief review of previous
work is presented in Section 2, all the adopted methods and mod-
els are described in Section 3, the results and discussions can be
found in Section 4, and conclusions drawn from the simulation are
listed in Section 5.
0364-5916/$ – see front matter © 2012 Elsevier Ltd. All rights reserved.
doi:10.1016/j.calphad.2012.02.002