Agriculture, Ecosystems and Environment 87 (2001) 273–285 Effects of elevated CO 2 and O 3 on tuber quality in potato (Solanum tuberosum L.) Alison Donnelly a , Tracy Lawson b , Jim Craigon a, , Colin R. Black a , Jeremy J. Colls a , Geoff Landon a a University of Nottingham, Sutton Bonington Campus, Loughborough LE12 5RD, UK b Department of Biological Sciences, John Tabor Laboratories, University of Essex, Wivenhoe Park, Colchester CO4 3SQ, UK Received 3 July 2000; received in revised form 30 October 2000; accepted 17 November 2000 Abstract This study examined the effects of season-long exposure to elevated carbon dioxide (CO 2 ) and/or ozone (O 3 ) on tuber quality in potato (Solanum tuberosum L. cv. ‘Bintje’). Stands of potato were grown to maturity in open-top chambers (OTCs) in 1998 and 1999 under a factorial combination of three CO 2 (ambient, 550 and 680 mol mol -1 ) and two O 3 levels (ambient and elevated; 8 h per day seasonal means of 50 and 65 nmol mol -1 in 1998 and 1999, respectively). The intermediate CO 2 concentration was omitted from analysis of tuber quality. In 1999, the starch content of tubers and the viscosity of the resulting paste were increased by elevated CO 2 (P< 0.05). Tuber nitrogen content was reduced by elevated CO 2 in both years (P< 0.05), but nitrate content was decreased only in 1999 (P< 0.05). Elevated CO 2 reduced citric acid content in 1998 (P< 0.05) and increased Vitamin C content in 1999 (P< 0.05). Elevated CO 2 also tended to decrease the total glycoalkaloid content of tubers (P< 0.08) by decreasing their -chaconine content. Elevated O 3 had less marked effects on tuber quality even though AOT40 values (accumulated O 3 exposure above a threshold of 40 nmol mol -1 ) of 12,461 and 27,113 nmol mol -1 h were applied in 1998 and 1999, respectively. In 1998 the paste produced from tubers produced under elevated O 3 was more viscous (P< 0.05) and in 1999 the starch granules were less resistant to swelling (P< 0.05) than in tubers produced under ambient O 3 . Total glycoalkaloid content was increased in 1999 because of an increase in -solanine content (P< 0.05). No CO 2 × O 3 interactions were detected for any of the quality parameters examined. The results are discussed in the context of the likely effects of predicted changes in climatic conditions on tuber quality. © 2001 Elsevier Science B.V. All rights reserved. Keywords: Carbon dioxide; Ozone; Potato; Solanum tuberosum L.; Tuber quality; Open-top chambers (OTCs); United Kingdom 1. Introduction Future climatic conditions are likely to differ appre- ciably from those currently experienced (IPCC, 1996). Corresponding author. Tel.: +44-115-951-6252; fax: +44-115-951-6334. E-mail address: jim.craigon@nottingham.ac.uk (J. Craigon). Atmospheric carbon dioxide (CO 2 ) concentration has increased from 290 mol mol -1 in pre-industrial times to ca. 370 mol mol -1 , and is expected to reach ca. 550 mol mol -1 by the middle of the present cen- tury (Houghton et al., 1992; Schimel et al., 1996). Tropospheric ozone (O 3 ) concentration is also ris- ing at an annual rate of ca. 0.5% (Hertstein et al., 1995); O 3 is not only a “greenhouse gas”, but is also 0167-8809/01/$ – see front matter © 2001 Elsevier Science B.V. All rights reserved. PII:S0167-8809(01)00144-X