ISSN 0003-6838, Applied Biochemistry and Microbiology, 2012, Vol. 48, No. 8, pp. 667–684. © Pleiades Publishing, Inc., 2012.
Original Russian Text © A.N. Nozhevnikova, M.V. Simankova, Yu.V. Litti, 2011, published in Biotekhnologiya, 2011, No. 5, pp. 8–31.
667
In the modern world, the amount of generated
wastewater is ever increasing as a result of domestic
and industrial activity, which demands an efficient and
cheap method of decontamination. The basis for bio-
logical decontamination of wastewater, which remains
the most economical and environmentally friendly
process, is aerobic and/or anaerobic degradation and
mineralization of organic matter by microorganisms.
The development and improvement of the existent
methods of biological decontamination of wastewater
from pollution is an extremely important task, as the
wastewater that gets into the environment affects the
quality of fresh water drastically. The global problem of
drinking water is inseparable from the problem of
wastewater treatment and prevention of the contami-
nation of fresh water.
Ammonium nitrogen is one of the major nutrients
contained in wastewater. The decontamination of
wastewater from nitrogen compounds is performed in
the nitrification–denitrification process, where
ammonium is first oxidized to nitrate, which is fol-
lowed by the assimilation of carbon dioxide (nitrifica-
tion) and subsequent reduction of nitrate to nitrogen
gas (denitrification) [1]. The process of nitri-denitrifi-
cation is quite expensive because of the high costs of
aeration and nutrients, which are needed for the
growth of denitrification microorganisms. The energy
consumption for aeration, which is needed for the
nitrification stage, could be as high as 80% of the total
energy consumption (nitrification–denitrification)
[2]. If the treated water does not contain a sufficient
source of organic carbon, the addition of electron
donors could be needed at the denitrification stage.
Nitrification–denitrification technologies are used for
the treatment of wastewater that have both an organic
content and a low nitrogen content. Thus, the process
of denitrification is used for urban wastewater treat-
ment where the initial BOC
5
/nitrogen ratio is not less
Application of the Microbial Process of Anaerobic Ammonium
Oxidation (ANAMMOX) in Biotechnological Wastewater Treatment
A. N. Nozhevnikova, M. V. Simankova, and Yu. V. Litti
Vinogradskii Institute of Microbiology, Russian Academy of Sciences, Moscow, 117312 Russia
e-mail: nozhevni@mail.ru, msimankova@mail.ru
Received July 6, 2011
Abstract—This review covers various aspects of the process of anaerobic ammonium oxidation by nitrite with
the formation of molecular nitrogen called ANAMMOX (ANaerobic AMMonium Oxidation). Anaerobic
ammonium oxidizing bacteria are briefly described, including their phylogenetics, habitat, and morphologi-
cal and physiological characteristics. The current views on the biochemistry of the microbial nitrite reduction
by ammonium are presented. The review is focused on biotechnological wastewater treatment based on the
ANAMMOX process. Various nitrogen removal technologies using this process, namely, the SHARON-
ANAMMOX CANON and DEAMOX BC-DEAMOX, and their practical use are reviewed. Various types of
reactors and set ups using the ANAMMOX process that are applied to the treatment of wastewater are ana-
lyzed. Processing methods for slowly growing ANAMMOX bacterial biomass accumulation aimed at subse-
quent inoculation in reactors are analyzed. The problems and methods for ANAMMOX bacterial biomass
immobilization in reactors and on carriers are described. A description and parameters of laboratory and pilot
plants utilizing various high-ammonia wastewater are given. Examples of the currently operating full-scale
industrial setups with the ANAMMOX process implementation, including those for the complex biochemi-
cal treatment of domestic sewage (BC-DEAMOX) constructed by EKOS (Russia) at the Olympic facilities in
the Sochi region, are discussed.
Keywords: ANAMMOX, ANAMMOX bacteria, anaerobic ammonium oxidation, BC-DEAMOX,
DEAMOX, denitrification, nitrification, wastewater decontamination, planctomycetes, CANON,
SHARON-ANAMMOX
DOI: 10.1134/S0003683812080042
Abbreviations: AOB, ammonium-oxidizing bacteria; BOD, bio-
logical oxygen demand; VFA, volatile fatty acids; NOB, nitrite-
oxidizing bacteria; IRBC, immersed rotating biological contrac-
tor; DM, dry matter; MSW, municipal solid waste; COD, chemi-
cal oxygen demand; ABF reactor, anaerobic biological filtrated
reactor; CANON, completely autotrophic nitrogen removal over
nitrite; DEAMOX, denitrifying ammonium oxidation; FISH, flu-
orescent in situ hybridization; RBC, rotating biological contac-
tor; SBR, sequential batch reactor; SHARON, single-reactor
high-activity ammonium removal over nitrite; UASB reactor, up-
flow anaerobic sludge blanket reactor.
PROBLEMS,
PERSPECTIVES