Cent. Eur. J. Eng. • 1(1) • 2011 • 81-88
DOI: 10.2478/s13531-011-0011-z
Central European Journal of Engineering
Prediction of Moisture Content of Natural Gases Using
Simple Arrhenius-type Function
Research Article
Alireza Bahadori
∗
School of Chemical and Petroleum Engineering,
Curtin University, GPO Box U1987,
Perth, WA, 6845 Australia
Received 22 January 2011; accepted 16 February 2011
Abstract: Natural gas extracted from underground reservoirs is saturated with water. The accurate prediction of moisture
content in natural gas is extremely important. The presence of water vapor can lead to potentially disastrous
consequences. The lifetime of a pipeline is governed by the rate at which corrosion occurs, which is directly
linked to the available moisture in the gas resulting in oxidation. In addition, the formation of hydrates due to
presence of water in natural gas can lead to safety hazards to production/transportation systems and to substantial
economic risks. In this paper, an attempt has been made to develop an easy-to-use Arrhenius-type asymptotic
exponential function combined with the Vandermonde matrix to arrive at an appropriate estimation of saturated
water content of sour natural gases for pressures up to 69000 kPa and the temperature range between 20 to
180˚C. Percent average absolute deviation of the proposed method is found to be around 2%, demonstrating the
excellent performance of the developed predictive tool. The tool will be of great practical value for chemical and
petroleum engineers to have a quick check on the water content of sour natural gases at various temperatures
and pressures without performing any experimental measurements.
Keywords: Natural gas • water content • Arrhenius function • predictive tool • Vandemonde matrix • Matlab program
© Versita Sp. z o.o.
1. Introduction
Moisture removal is a key stage of natural gas condi-
tioning and processing prior to sale and its efficiency is
important in order to satisfy fiscal contractual obligations
and to ensure that the gas is safe to transport and con-
tains the right properties for subsequent use [1]. When
the gas is produced there is a simultaneous production of
water as well. Some of this water is produced water from
∗
E-mail: alireza.bahadori@postgrad.curtin.edu.au, Tel: +61 8 9266 1782,
Fax: +61 8 9266 2681
the reservoir directly [2]. In the transmission of natural
gas, further condensation of water is problematic. It can
increase pressure drop in the line, often leading to corro-
sion problems and gas hydrate formation [1, 2] which can
reduce pipeline flow capacities, blockages and potential
damage to process filters, valves and compressors. Such
hydrates are caused by the combination of excessive wa-
ter vapor with liquid hydrocarbons, which may condense
out of the gas in the course of transmission to form emul-
sions that, under process pressure conditions, are solid
masses. There are numerous methods available for deter-
mining water content of natural gases [3–8]. In some of
these models the vapor pressure of pure water is required
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