International Journal of Drug Delivery 1(2009) 15-26
http://www.arjournals.org/ijodd.html
Research article ISSN: 0975-0215
Development and in vitro evaluation of polar lipid based lipospheres
for oral delivery of peptide drugs
Manju Rawat Singh
1
*, Deependra Singh
1
, Saraf Swarnlata
1
*Corresponding author:
Manju Rawat Singh
1
Institute of Pharmacy,
Pt Ravishankar Shukla
University,
Raipur (C.G.), INDIA-
492010
Tel: ++91-771-2262832 Off),
++91-771-2262832 (Fax)
E-mail:
manjursu@rediffmail.com
Abstract
A 3
2
factorial design was employed to produce oral sustained release
lipospheres prepared by modified double emulsion solvent evaporation
technique for Serratiopeptidase (acid-labile enzyme) using wax and polar
lipid combination as retardants. The effects of formulation variables selected
through preliminary trials namely peptide and stabilizer (Tween® 80)
concentration was evaluated by F-test on the drug content and size of
lipospheres. The results of analysis of variance tests for both effects indicated
that the test is significant (p < 0.05). The effect of Tween® 80 concentration
(SSY
1
- 41.66; SSY
2
– 25.30) was found to be higher than peptide amount
(SSY
1
- 3.94; SSY
2
– 4.03) on the size and drug content of lipospheres.
Characterization was carried out through photomicroscopy, scanning electron
microscopy, particle size analysis and in vitro drug release study. The effect
of formulation variables on the integrity of enzyme was confirmed by in vitro
proteolytic activity. The drug release from lipospheres followed first-order
kinetics and was characterized by the Higuchi diffusion and Ritger-Peppas
model. Lipospheres having maximum drug content (11.93±0.89) released 3-
4% enzyme at pH 1.2 in 4 h. In phosphate buffer, lipospheres showed an
initial burst release of 20.89±1.87% to 27.89±2.03% in one hour with
additional 73.22±2.36% to 94.75±2.78% in next 12 hours. Thus, peptide
loaded lipospheres with desirable characters in terms of maximum peptide
content and diffusion release pattern were successfully prepared with
formulation optimization approach.
Keywords: Cetyl alcohol, Enzyme, factorial design, Lipospheres; Peptide,
Serratiopeptidase
Introduction
Proteins and polypeptides are important classes of
bioactive agents that play key roles in controlling
various body functions required for good health when
administered in the correct quantities at the appropriate
body site and at the correct time. Proteins and peptides
have many attractive properties but they also have
disadvantages that limit their widespread acceptance by
patients and physicians such as numerous chemical and
physical instability mechanisms, rapid enzymatic
degradation which is responsible for low oral and
transdermal bioavailability and short in vivo half lives,
doi:10.5138/ijdd.2009.0975.0215.01002
15
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