Electrochemical Noise Analysis for Nylon/Titanium Hybrid Materials
C. Menchaca-Campos
a,b,*
, S. Hernandez-del Fabbro
a
, E. Sarmiento-Bustos
c
, R. Cruz-
Silva
a
, M.A. García-Sánchez
b
, D. Bahena
a
, J. Uruchurtu
a
a
Centro de Investigación en Ingeniería y Ciencias Aplicadas, UAEM, Av.
Universidad 1001, Col Chamilpa, C.P. 62209, Cuernavaca Mor., México
b
UAM-Iztapalapa. Depto. de Química. Av. San Rafael Atlixco 186, Vicentina, 09340
D.F., México
c
Universidad Tecnológica Emiliano Zapata del Estado de Morelos, Av. Universidad
No.1 Col. Palo Escrito, C.P. 62790, Emiliano Zapata, Mor. México
Development of hybrid materials is a necessity. Polymeric
materials are widely used in industry because their superior
properties. In this work, synthesis, characterization and
electrochemical noise evaluation of hybrid materials casted from
nylon 6-6 and titanium are involved. Synthesis was carried out with
30, 40 and 50% wt of titanium functionalized with APTES. The
materials obtained were characterized through scanning electron
microscopy (SEM), thermal analysis (TA), infrared spectroscopy
(IR) and electrochemical noise technique in Hank solution to
simulate the internal fluids of the human body, in terms of
biomaterial application, amongst others. SEM shows a
homogenous material. Concentration of titanium was verified with
TA. IR spectra show differences between Ny-Ti at different
concentrations. Hybrid material made with 50%wt titanium present
the lower resistance and the 30% wt the highest, as electrochemical
noise resistance confirms. All samples show high resistivity in
atmospheric conditions, while in Hank solution electrochemical
characteristics were observed.
Introduction
“If the XIX century was the ceramics and the XX the polymers, the XXI will be the
hybrid century”. Materials that have both an organic and an inorganic part are called
hybrids. In nature there exist a lot of this kind of materials, may be bonds are the most
noticeable, because they have very good qualities, like: hardness and strength that no
other synthetic material owns [1].
Polyamides, nylon in particular are great impact polymers in the industry, and had
been experience a huge evolution in their synthesis. Conjunction of nylon and a metal
capable of make compatible these polymeric materials with the human body environment
have been developed in the scientific field in the last years [2].
From the time when nylon 6,6 was discovered, a great interest had been generated,
not just because its technological importance due to their commercial character, but
ECS Transactions, 36 (1) 83-92 (2011)
10.1149/1.3660601 ©The Electrochemical Society
83
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