Influence of fuel and condition in combustion synthesis on properties of
copper (II) oxide nanoparticle
Hamed Sadabadi
1,a*
, Adeleh Aftabtalab
2,b
, Shirzad Zafarian
1,c
,
Ch.Shilpa Chakra
1,d,
K. Venkateswara Rao
1,e
,Sarah Shaker
1,f
,
1
Centre of Nano Science and Technology, Institute of Science and Technology, Jawaharlal Nehru
Technological university of Hyderabad, AP, India
2
Centre for Environment, Institute of Science and Technology, Jawaharlal Nehru Technological
university of Hyderabad, AP, India
a
hamed.sadabadi@gmail.com,
b
adeleh.aftabtalab@gmail.com,
c
shirzad80@gmail.com,
d
shilpachakra@jntuh.ac.in,
e
kalagadda2003@gamail.com,
f
srh.shaker@gmail.com
Keywords: copper (II) oxide, CuO nanostructure, combustion synthesis.
Abstract: Copper oxide nanoparticles have been received attraction due to their unique properties
and potential future applications. In present work nanostructure Copper (II) oxide (CuO) spherical
nanoparticle synthesized by solution combustion method and the influence of different fuel and
condition on the properties of CuO particle was investigated. Crystalline phase and size indicated
by applying XRD and particle size distribution studied further using DLS. Scanning electron
microscopy (SEM) was used for morphological study and EDAX analysis shows composition of
CuO particles. Nanostructure of copper (II) oxide particle studied further by Transmission electron
microscopy (TEM) and selected area electron diffraction (SAED) applied for detail study on
crystalline structure of particles.
Introduction
Copper (II) oxide nanoparticle known as p-type semiconductor, with a direct band gap [1], is a
low-cost material for photovoltaic devices [2], and it has been used widely in variety of applications
such as: electrode materials for lithium-Iron battery[3],solar-energy transformation [4], gas's sensor
[5]. During the past decade, different types of CuO nanostructures have been prepared, which
involve multiple steps that were not efficient. Properties of materials at nanoscale, strongly depend
on their shape and dimensions [6-9]. Recently Copper Oxide nanostructured, such as: nanotubes,
nanorods [10], nanowires [11], nanorings, nanoribbones [12] and nanobelts have received attraction
due to their fundamental importance and potential future applications [13-16]. Number of
techniques such as: Chemical Vapor Deposition, Physical Vapor Deposition, Sol-gel, hot-soap,
pyrolysis, and spray pyrolysis methods for the preparations of nanoparticles have been developed
[17]. All these techniques require special equipments [18]. Industrial processes need to be time
efficient, low-cost, continuous operation and high production rate. Solution Combustion synthesis
(CS) is a time-consuming and cost-efficient method to produce various industrially metal oxides
[19]. Solution method has been attracted more interesting as a safety and environmental friendly
route for the large-scale production of CuO nanostructures [20].Preparation of spherical
homogenous CuO nanoparticle, using sono-chemical method also needed calcination at high
temperature (600-700
o
C) [21]. In this work copper (II) oxide nanostructure was synthesized and
influence of fuel and condition in combustion synthesize on size, morphology, and crystallinity of
CuO was investigated.
Experimental procedure
Materials:
Copper nitrate nonahydrate extra pure provided from E. merck (India) limited Co. Urea extra pure
and Glycine extra pure purchased from Finer chemicals limited Co (India).
Advanced Materials Research Vol. 829 (2014) pp 152-156
© (2014) Trans Tech Publications, Switzerland
doi:10.4028/www.scientific.net/AMR.829.152
All rights reserved. No part of contents of this paper may be reproduced or transmitted in any form or by any means without the written permission of TTP,
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