Materials Science and Engineering B 114–115 (2004) 251–254
Implant damage and redistribution of indium in
indium-implanted thin silicon-on-insulator
Peng Chen
a
, Zhenghua An
b
, Ming Zhu
a,b
, Ricky K.Y. Fu
a
, Paul K. Chu
a,∗
,
Neil Montgomery
c
, Sukanta Biswas
c
a
Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong
b
State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology,
Chinese Academy of Sciences, 865 Changning Road, 200050 Shanghai, China
c
Cascade Scientific, Brunel Science Park, Uxbridge, Middlesex UB83PH, UK
Abstract
The indium implant damage and diffusion behavior in thin silicon-on-insulator (SOI) with a 200 nm top silicon layer were studied for
different implantation energies and doses. Rutherford backscattering spectrometry in the channeling mode (RBS/C) was used to characterize
the implant damage before and after annealing. Secondary ion mass spectrometry (SIMS) was used to study the indium transient enhanced
diffusion (TED) behavior in the top Si layer of the SOI structure. An anomalous redistribution of indium after relatively high energy (200 keV)
and dose (1 × 10
14
cm
-2
) implantation was observed in both bulk Si and SOI substrates. However, there exist differences in these two substrates
that are attributable to the more predominant out-diffusion of indium as well as the influence of the buried oxide layer in the SOI structure.
© 2004 Elsevier B.V. All rights reserved.
Keywords: Indium; Implant damage; Diffusion; SOI; SIMOX
1. Introduction
As a heavy ion, indium has become a promising dopant
to achieve ultra-shallow or steep retrograde channel profiles
(SRCP) in advanced metal-oxide-semiconductor field-effect-
transistors (MOSFETs) [1–4]. However, due to its heavy
mass, implantation-induced damage is quite considerable
even at relatively low doses typically used in channel dop-
ing. Moreover, the poor electrical activation of indium in Si
due to the high ionization energy [5] and low solid solubility
[6] necessitate the implantation of a higher dose. The large
amount of ion implantation induced damage will affect both
indium diffusion during subsequent thermal processes and
the electrical characteristics of the final devices. Transient
enhanced diffusion (TED) of indium in Si has been observed
and the magnitude is comparable to that of boron [6–9], and
it poses one of the main challenges to form steep and shallow
profiles.
∗
Corresponding author. Tel.: +852 2788 7724;
fax: +852 2788 9549/7830.
E-mail address: paul.chu@cityu.edu.hk (P.K. Chu).
Silicon-on-insulator (SOI) substrates have many advan-
tages over bulk silicon in high-speed, low-power devices
[10–11] and indium implantation into SOI can further im-
prove the device performance. Although much research has
been devoted to indium implantation and diffusion in bulk
Si, that on indium implantation into SOI is relatively scarce.
In addition, although some dopants, such as boron and
phosphorus have been shown to exhibit different diffusion
behavior in SOI compared to bulk Si [12–14], detailed com-
parison between the diffusion of indium in SOI and bulk sil-
icon has not been carried out. In this work, the implantation
induced damage and indium diffusion characteristics were
studied. The SOI wafers used were separation by implanta-
tion of oxygen (SIMOX) wafers that are commonly used for
fully depleted metal-oxide-semiconductor field-effect tran-
sistors (MOSFETs) [15]. We investigated systematically the
indium ion implantation induced damage under different im-
plant energies and doses. The indium diffusion behavior in
the SOI structure, especially in the top Si layer, was also
studied, and the results were compared to those obtained in
bulk Si. The difference between the indium diffusion pro-
files in SIMOX and bulk Si implanted at a relatively high
0921-5107/$ – see front matter © 2004 Elsevier B.V. All rights reserved.
doi:10.1016/j.mseb.2004.07.031