Volume 3 • Issue 2 • 1000116
J Pet Environ Biotechnol
ISSN: 2157-7463 JPEB, an open access journal
Open Access Research Article
Petroleum & Environmental
Biotechnology
Nduka et al., J Pet Environ Biotechnol 2012, 3:2
http://dx.doi.org/10.4172/2157-7463.1000116
*Corresponding author: John Kanayochukwu Nduka, Environmental Chemistry
and Toxicology Research Unit, Pure & Industrial Chemistry Department,
Nnamdi Azikiwe University, P.M.B. 5025, Awka, Anambra State, Nigeria, E-mail:
johnnduka2000@yahoo.co.uk
Received December 17, 2011; Accepted February 20, 2012; Published February
22, 2012
Citation: Nduka JK, Umeh LN, Okerulu IO, Umedum LN, Okoye HN (2012)
Utilization of Different Microbes in Bioremediation of Hydrocarbon Contaminated
Soils Stimulated With Inorganic and Organic Fertilizers. J Pet Environ Biotechnol
3:116. doi:10.4172/2157-7463.1000116
Copyright: © 2012 Nduka JK, et al. This is an open-access article distributed under
the terms of the Creative Commons Attribution License, which permits unrestricted
use, distribution, and reproduction in any medium, provided the original author and
source are credited.
Abstract
Different microbes (E.coli, Proteus, Klebsiella and Pseudomonas sp) were utilized in degradation of different
hydrocarbon (Engine oil/diesel, kerosene and fuel) contaminated soils amended with inorganic (NPK and urea) and
organic (cow dung and poultry litter) fertilizers and in some their combination. The incubation period ranged from
3 – 18 days. Bacterial population count and residual hydrocarbon were determined .Results showed that bacterial
population count increased as the microbes utilized hydrocarbon for carbon and energy sources, the increase in
population count and degradation of the hydrocarbons was stimulated by the fertilizer. It was also observed that
as the population count increased due to hydrocarbon utilization for carbon and energy, residual hydrocarbon
decreased and percentage degradation increased. Urea fertilizer was the best amendment for E.coli to degrade
kerosene, NPK and cow dung differently aided the same E.coli in degrading engine oil. Pseudomonas and Proteus
species degraded kerosene and fuel better in the presence of NPK fertilizer. Klebsiella specie degraded diesel and
engine oil better when amended with poultry litter and cow dung respectively at least for the irst 9 days. More than
90% of the hydrocarbons were degraded within each incubation period. The microbes began to die as from the 15
th
day of incubation, this may be due to secretion of toxic secondary metabolites. Control experiments revealed that
there was initial increase in population count of the microbes as they utilized the hydrocarbon for carbon and energy,
but they began to die because of non-stimulation with fertilizer, therefore less than 50% of the hydrocarbons were
degraded in all the control experiments. Maize seeds grew on the remediated soil within six (6) days of planting.
Utilization of Different Microbes in Bioremediation of Hydrocarbon
Contaminated Soils Stimulated With Inorganic and Organic Fertilizers
John Kanayochukwu Nduka*, Linda Nkechi Umeh, Isaac Obi Okerulu, Lilian Ngozi Umedum and Helen Nkechi Okoye
Environmental Chemistry and Toxicology Research Unit, Pure & Industrial Chemistry Department, Nnamdi Azikiwe University, P.M.B. 5025, Awka, Anambra State, Nigeria
Keywords: Biodegradation; Bioremediation; Microbes;
Hydrocarbon; Fertilizer; Contaminated soil
Introduction
he world, in which we live as it is today, is the world in which
everything we do as regards human growth, biological, physical,
economic, industrial and infrastructural growth, science and
technological growth etc. revolves around energy. Apart from the
traditional irewood, wind and hydro power, petroleum hydrocarbon
continues to be used as the most principal and versatile source of
energy and therefore an important global environmental pollutant
[1]. Crude oil or petroleum hydrocarbon exploration and exploitation
which came ater industrial revolution stems from advances in science
and technology which have enabled humans to exploit their natural
resources, although not without a cost, as it has generated unprecedented
disturbances in global elemental cycles [2]. he relatively sudden
introduction of xenobiotic chemicals as well as the massive relocation
of natural materials to diferent environmental compartments can
oten overwhelm the self cleaning capacity of recipient ecosystems
and therefore result in the accumulation of pollutants to problematic
or even harmful levels [3]. Bioremediation plays a great role in
solving some of these problems. Bioremediation is the application of
biological treatment to clean up hazardous chemicals. his process
involves detoxiication where the pollutant may be converted to less
toxic substances and mineralization, where the waste material can be
converted into inorganic compounds such as carbon dioxide, water,
methane and sometimes fatty acids [4]. Bioremediation is not new to
human race but new approaches that stem from advances in molecular
biology and process engineering are emerging. Microbes bioremediate
the environment as they biodegrade the pollutant to obtain carbon
and energy, Biodegradation speciically refers to chemical breakdown
or mineralization of materials facilitated by biological organisms or
products [5]. Contamination of the environment with petroleum
hydrocarbons has caused critical health defects and therefore
increasing attention has been focused on developing and implementing
innovative technology for cleaning up this contamination [3,6]. When
oil spillages occur as with the cases in the Niger-delta region of Nigeria
, concerted eforts are made to remove, remediate or recover the
spilled oil immediately, but when the spill is small as in automobile
workshops, gasoline petrol station, and during tanker, loading or
of-loading operations at the reinery or during clean-up operations,
the possible efect is that it may be ignored, but on continuous and
prolonged spill as the case has been, contamination of ground water
and air due to evaporation is possible because of its persistence.
Bioremediation methods therefore come in handy and have correctly
received favorable publicity as promising environmentally friendly
technique for the remediation of hydrocarbon contaminated ecosystem
[7]. his is possible because microorganisms have enzyme system to
degrade and utilize diferent hydrocarbon as a source of carbon and
energy [8]. A number of gram positive and negative microbes have
been reported to be capable of utilizing a wide variety of hydrocarbons
as carbon and energy [9]. he microorganisms include bacteria of
the genera Klebsiella, Proteus, Bacillus, Escherichia, Pseudomonas,
Streptomyces, Nocardia, Seratia, Xanthomonas, Micrococcus etc. and