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Superlattices and Microstructures ( ) –
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Superlattices and Microstructures
journal homepage: www.elsevier.com/locate/superlattices
Novel ultrasonic-assisted alignment of L1
0
FePt nanoparticles
S. Foglia
a,∗
, A. Notargiacomo
a
, A. Capobianchi
b
, A.M. Testa
b
, D. Fiorani
b
,
L. Arrizza
c
, C. Veroli
d
a
Istituto di Fotonica e Nanotecnologie, CNR, 00146 Roma, Italy
b
Istituto di Struttura della Materia, CNR, Montelibretti, Roma, Italy
c
Università degli Studi dell’Aquila, Centro di Microscopia Elettronica, L’Aquila, Italy
d
Istituto di Studio Materiali Nanostrutturati, CNR, Montelibretti, Roma, Italy
article info
Article history:
Available online xxxx
Keywords:
Magnetic nanoparticles
Assembling
abstract
Chemically ordered (L1
0
) FePt nanoparticles were synthesized
by a microemulsion technique and the ordered phase was
obtained by heating a mixture of particles and lyophilized NaCl
as the separating medium, avoiding coalescence. A chloroform
suspension of L1
0
FePt nanoparticles was evaporated at room
temperature, assisted by ultrasonic vibration, producing the
arrangement of the particles on the substrate. Parallel lines and
flower-like patterns were obtained, starting from a 4 × 10
−3
M
suspension and using higher dilutions, suggesting that the fast
evaporation of chloroform allows the particles deposition on the
substrate, following the propagation direction of the ultrasound
waves and/or placement at a vibration node, depending on the
concentration.
© 2008 Elsevier Ltd. All rights reserved.
FePt-based nanostructured materials are promising candidates for future ultrahigh density
recording media because of their good chemical stability and high magnetocrystalline anisotropy
(∼10
8
erg/cm
3
) observed in the ordered face-centred tetragonal (fct) L1
0
phase [1,2]. This large
magnetocrystalline anisotropy allows nanometric grains to be thermally stable over typical data
storage periods of 10 years. A well-organized magnetic array of such particles should contribute to
efforts to design magnetic media capable of increasing densities well beyond 1 Tbit/in
2
[3].
∗
Corresponding author. Tel.: +39 0657333343.
E-mail address: sabrina.foglia@ism.cnr.it (S. Foglia).
0749-6036/$ – see front matter © 2008 Elsevier Ltd. All rights reserved.
doi:10.1016/j.spmi.2008.11.001
Please cite this article in press as: S. Foglia, et al., Novel ultrasonic-assisted alignment of L1
0
FePt nanoparticles, Superlattices
and Microstructures (2008), doi:10.1016/j.spmi.2008.11.001