Jointly published by React.Kinet.Catal.Lett.
Akadémiai Kiadó, Budapest Vol. 91, No. 1, 131−139 (2007)
and Springer, Dordrecht 10.1007/s11144.007.5072.x
0133.1736/2007/US$ 20.00.
© Akadémiai Kiadó, Budapest.
All rights reserved.
RKCL5072
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Chemistry Department, Yarmouk Unversity, P.O.Box 566, Irbid, Jordan
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Hydrogenation of phenylpropanal over Ir was investigated under mild conditions.
An LH.kinetic model is presented that describes successfully experimental results
specially the negative effects of temperature and initial concentrations.
: Hydrogenation, phenylpropanal, iridium, kinetics
Cinnamyl alcohol (III) is a much valued substance in the fragrance,
pharmaceutical and fine chemical industries. Its production via the
heterogeneously catalyzed selective reduction of cinnamaldehyde over platinum
group metals, although superior over conventional methods in saving resources
and reducing waste material, is for thermodynamic and kinetic reasons of limited
application. Various approaches have been tested in an attempt to improve the
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* Corresponding author. E.mail: ayman@yu.edu.jo