Effects of Isoflurane on Voltage-Dependent Calcium Fluxes in Rabbit T-Tubule Membranes: Comparison with Alcohols Murat Oz,* ,1 Yulia Tchugunova,† Meral Dinc,† and Susan M. J. Dunn‡ *Cellular Neurobiology Section, National Institute on Drug Abuse, 5500 Nathan Shock Drive, Baltimore, Maryland 21224; Department of Pulmonary Diseases, Oncological Hospital, Ankara 06947, Turkey; and Department of Pharmacology, University of Alberta, Edmonton, Alberta T6G 2H7, Canada Received October 1, 2001; published online January 21, 2002 The effects of racemic () and ()- and ()-stereoiso- mers of isoflurane on depolarization-induced 45 Ca 2 fluxes mediated by voltage-dependent Ca 2 channels were investigated in transverse tubule membrane ves- icles from rabbit skeletal muscle. In the concentration range 0.5 to 2 mM, ()-isoflurane inhibited 45 Ca 2 fluxes and functionally modulated the effects of the Ca 2 channel antagonist nifedipine (1–10 M). Isoflu- rane-induced inhibition of 45 Ca 2 fluxes was not signif- icantly affected by pretreatment with either pertussis toxin (5 g/ml) or phorbol 12-myristate 13-acetate (50 nM). Further experiments indicated that there were no significant differences between ()- and ()-stereo- isomers of isoflurane with respect to the extent of in- hibition of 45 Ca 2 fluxes. Radioligand binding studies indicated that racemic and ()- and ()-isoflurane were equally effective in displacing the specific bind- ing of [ 3 H]PN 200-110 to transverse tubule membranes. There were no apparent differences between the ef- fects of ()- and ()-isoflurane on the characteristics of [ 3 H]PN 200-110 binding. Although the concentra- tions of isoflurane for the inhibitions of 45 Ca 2 fluxes and radioligand bindings were similar, the concentra- tions of n-alcohols required for the inhibition of 45 Ca 2 fluxes were lower than those for the displacement of radioligand. Comparison of the data for the displace- ment of [ 3 H]PN 200-110 binding and the inhibition of 45 Ca 2 fluxes by isoflurane and by n-alcohols suggested that both isoflurane and n-alcohols may have more than a single binding site. In conclusion, results indi- cate that isoflurane, independent of intracellular Ca 2 levels, nonstereospecifically inhibits the function of voltage-dependent Ca 2 channels and this effect is me- diated through multiple binding sites. © 2002 Elsevier Science (USA) Key Words: calcium channels; volatile anesthetics; stereoisomers; alcohols; skeletal muscle. In the search of potential targets for the cellular and molecular actions of volatile anesthetics, a number of ion channels have been investigated (for a review, see 1). In previous studies it has been reported that volt- age-dependent Ca 2+ channels (VDCCs) 2 of neurons, smooth and cardiac muscles are affected by these com- pounds (2– 4). The VDCC of skeletal muscle is the best characterized Ca 2+ channel subtype in terms of its molecular structure (5) but there has been no report on the effect of volatile anesthetics on its function. Fur- thermore, observations that volatile anesthetics can have multiple effects at various levels of cellular func- tion complicate the interpretation of some of the earlier findings in which intact cells were used. For example, volatile anesthetics have been shown to release Ca 2+ from intracellular stores of several cell types including cultured neurons and cardiac and skeletal muscle fi- bers (6 – 8). Since VDCCs are inactivated by rises in intracellular Ca 2+ (9 –11), it is possible that some of the effects of volatile anesthetics are mediated by increases in intracellular Ca 2+ concentrations. Furthermore, vol- atile anesthetics have been shown to directly and/or indirectly (via increases in intracellular Ca 2+ concen- trations) activate several second messenger systems including protein kinases C and A and calmodulin (12, 13) which are known to affect the functional properties of VDCCs. Thus the possible secondary effects of vola- 1 To whom correspondence should be addressed. Fax: (410) 550- 1621. E-mail: moz@intra.nida.nih.gov. 2 Abbreviations used: VDCC, voltage-dependent Ca 2+ channel; T, transverse; EGTA, ethylene glycol bis (-aminoethyl ether) N, N'- tetraacetic acid; DMSO, dimethyl sulfoxide; PMA, phorbol 12-myris- tate 13-acetate; ANOVA, analysis of variance; PTX, pertussis toxin; DHP, 1,4-dihydropyridine; PN 200-110, isradipine. 0003-9861/02 $35.00 275 © 2002 Elsevier Science (USA) All rights reserved. Archives of Biochemistry and Biophysics Vol. 398, No. 2, February 15, pp. 275–283, 2002 doi:10.1006/abbi.2001.2726, available online at http://www.idealibrary.com on