Molecular and Cellular Endocrinology 252 (2006) 136–141 The steroidogenic effect of single-chain bovine LH analogs in cultured bovine follicular cells Ruth Braw-Tal a , Svetlana Pen a , Moran Grinberg b , Sigal Nakav b , David Ben-Menahem b, a Institute of Animal Science, Agricultural Research Organization, The Volcani Center, Beit Dagan 50250, Israel b Department of Clinical Pharmacology, Faculty of Health Sciences, Ben–Gurion University of the Negev, Beer-Sheva 84105, Israel Abstract Single-chain gonadotropin analogs had been constructed for the purpose of structure–function studies and analog design. Incorporation of a spacer derived from the carboxyl terminal peptide (CTP) of the choriogonadotropin (CG) subunit between the tethered subunit domains of the human gonadotropins is beneficial for the secretion of the single-chain variants without compromising biocactivity. Although the CGsubunit containing the CTP domain is expressed only in primates and equids, a CTP-like sequence exists in the untranslated region of the LHgene of several mammalian species, including the bovine species. The CTP encrypted in the bovine LHDNA (designated as ‘boCTP’) and the CTP derived from the human CGsubunit (denoted as ‘huCTP’) served as a linker sequence in the design of bovine single-chain luteinizing hormone (LH) analogs. The purpose of the present study was to evaluate steroidogenesis in cultured bovine theca cells following stimulation with these single- chain analogs. The concentration of the LHboCTPand LHhuCTPanalogs in the conditioned media of the expressing CHO cells was three- to six-fold higher than that of the “linkerless” LH and LH111variants. The four analogs induced androstenedione and progesterone secretion from the primary theca cells in a dose-dependent manner, but differences in the steroidogenic response were observed. The LHboCTPanalog (10 ng/ml) effectively induced androstenedione and progesterone secretion over unstimulated levels (4.0- and 4.4-fold increase for androstenedione and progesterone, respectively). The response to the pituitary bovine LH standard (10 ng/ml) was less pronounced for both steroids (two- to three-fold increase over basal levels). The activities of LHhuCTP, LH and LH111were comparable and sightly reduced relative to the LHboCTPactivity. The data suggested that LHboCTPwas ranked as the most potent and this was even more prominent when analogs were used at a lower dose (1ng/ml). These data suggest that the design, including the huCTP or boCTP linker, is favorable for the production of single-chain bovine LH analogs. Furthermore, spacing of the tethered subunit domains with the cryptic boCTP sequence that originated from the bovine LHgene appears advantageous for the purpose of stimulating steroid production in the species-specific bioassay. Thus, an effective strategy to produce bioactive single-chain LH analogs in non-primate, non-equid species would be the mutatation of the LHgenes with the aim of expressing the cryptic CTP sequence as a spacer derived from the DNA of the same organism. © 2006 Elsevier Ireland Ltd. All rights reserved. Keywords: Bovine LH; Single chain analogs; CTP; Cryptic CTP; Theca cells; Species-specific bioassay 1. Introduction The pituitary gonadotropins, luteinizing hormone (LH), fol- licle stimulating hormones (FSH) and the placental chorionic gonadotropin (CG) that is produced in primates and equids, are regulators of steroid production in the ovary and testis. Each of these glycoproteins is a non-covalent heterodimer, com- posed of a common subunit and a unique subunit that confers the receptor-specificity. The heterodimer, but not the monomeric subunits, efficiently binds and activates the cognate receptor (Pierce and Parsons, 1981). In order to bypass the rate- Corresponding author. Tel.: +972 8 6477485; fax: +972 8 6477629. E-mail address: dbm@bgumail.bgu.ac.il (D. Ben-Menahem). limiting assembly step, to expand the arsenal of muteins for structure–function studies and analog design, and to combine various activities in a single polypeptide single chain, analogs of the human glycoprotein hormones were genetically engineered by in tandem linking of the genes encoding the monomeric subunits (Narayan et al., 1995; Sugahara et al., 1995, 1996; Grossman et al., 1997; Kanda et al., 1999; Garcia-Campayo et al., 2005). Recently, the tethering approach was exploited to gonadotropins of additional species including equine, ovine, bovine and tilapia (Galet et al., 2001; Dirnberger et al., 2001; Fidler et al., 2003; Min et al., 2003; Kasuto and Levavi-Sivan, 2005; Nakav et al., in press). We previously engineered genetically the single-chain bovine LH variants, in which the and subunit domains were linked directly or via the heterologous huCTP (derived from the human 0303-7207/$ – see front matter © 2006 Elsevier Ireland Ltd. All rights reserved. doi:10.1016/j.mce.2006.03.011