Agricultural and Forest Meteorology 151 (2011) 1440–1452 Contents lists available at ScienceDirect Agricultural and Forest Meteorology j ourna l ho me pag e: www.elsevier.com/locate/agrformet Seasonal variation and fire effects on CH 4 , N 2 O and CO 2 exchange in savanna soils of northern Australia Stephen J. Livesley a,b, , Samantha Grover c , Lindsay B. Hutley c , Hizbullah Jamali b , Klaus Butterbach-Bahl d , Benedikt Fest b , Jason Beringer c , Stefan K. Arndt b a School of Geography and Environmental Science, Monash University, VIC, Australia b Department of Forest and Ecosystem Science, The University of Melbourne, VIC, Australia c School of Environmental and Life Sciences, Charles Darwin University, NT, Australia d Institute for Meteorology and Climate Research, Karlsruhe Institute of Technology, Kreuzeckbahnstr 19, 82467 Garmisch-Partenkirchen, Germany a r t i c l e i n f o Article history: Received 14 August 2010 Received in revised form 29 December 2010 Accepted 2 February 2011 Keywords: Methane Nitrous oxide Carbon dioxide Nitrification Fire Savanna woodland Termites Soil gas diffusion a b s t r a c t Tropical savanna ecosystems are a major contributor to global CO 2 , CH 4 and N 2 O greenhouse gas exchange. Savanna fire events represent large, discrete C emissions but the importance of ongoing soil- atmosphere gas exchange is less well understood. Seasonal rainfall and fire events are likely to impact upon savanna soil microbial processes involved in N 2 O and CH 4 exchange. We measured soil CO 2 , CH 4 and N 2 O fluxes in savanna woodland (Eucalyptus tetrodonta/Eucalyptus miniata trees above sorghum grass) at Howard Springs, Australia over a 16 month period from October 2007 to January 2009 using manual chambers and a field-based gas chromatograph connected to automated chambers. The effect of fire on soil gas exchange was investigated through two controlled burns and protected unburnt areas. Fire is a frequent natural and management action in these savanna (every 1–2 years). There was no seasonal change and no fire effect upon soil N 2 O exchange. Soil N 2 O fluxes were very low, generally between -1.0 and 1.0 g N m -2 h -1 , and often below the minimum detection limit. There was an increase in soil NH 4 + in the months after the 2008 fire event, but no change in soil NO 3 - . There was considerable nitrification in the early wet season but minimal nitrification at all other times. Savanna soil was generally a net CH 4 sink that equated to between -2.0 and -1.6 kg CH 4 ha -1 y -1 with no clear seasonal pattern in response to changing soil moisture conditions. Irrigation in the dry season significantly reduced soil gas diffusion and as a consequence soil CH 4 uptake. There were short periods of soil CH 4 emission, up to 20 g C m -2 h -1 , likely to have been caused by termite activity in, or beneath, automated chambers. Soil CO 2 fluxes showed a strong bimodal seasonal pattern, increasing fivefold from the dry into the wet season. Soil moisture showed a weak relationship with soil CH 4 fluxes, but a much stronger relationship with soil CO 2 fluxes, explaining up to 70% of the variation in unburnt treatments. Australian savanna soils are a small N 2 O source, and possibly even a sink. Annual soil CH 4 flux measurements suggest that the 1.9 million km 2 of Australian savanna soils may provide a C sink of between -7.7 and -9.4 Tg CO 2 -e per year. This sink estimate would offset potentially 10% of Australian transport related CO 2 -e emissions. This CH 4 sink estimate does not include concurrent CH 4 emissions from termite mounds or ephemeral wetlands in Australian savannas. © 2011 Elsevier B.V. All rights reserved. 1. Introduction The increased concentration in the atmosphere of greenhouse gases including carbon dioxide (CO 2 ), methane (CH 4 ) and nitrous oxide (N 2 O) as a result of anthropogenic activity is widely recog- nised as the cause of global climate warming and an increase in the Corresponding author at: Dept. of Resource Management and Geography, The University of Melbourne, Burnley campus, Richmond, Melbourne, VIC 3121, Australia. Tel.: +61 439 615 772. E-mail address: sjlive@unimelb.edu.au (S.J. Livesley). intensity and frequency of extreme weather events (IPCC, 2007). These gases are all naturally present in the atmosphere and cycle between the land, the ocean and the atmosphere over a range of time scales. Global climate models have been developed as tools to predict global biogeochemical cycling and climate systems, but their efficacy is limited by our understanding of the underlying pro- cesses which drive the cycling of greenhouse gases (Beringer et al., 2011), this is particularly so for CH 4 and N 2 O. Savanna ecosystems are a significant global biome and cover approximately one sixth of the earth’s land surface and have been estimated to produce 30% of the earth’s total net primary produc- tivity (Grace et al., 2006). Tropical savanna ecosystems have been 0168-1923/$ see front matter © 2011 Elsevier B.V. All rights reserved. doi:10.1016/j.agrformet.2011.02.001