1628 IEEE PHOTONICS TECHNOLOGY LETTERS, VOL. 19, NO. 20, OCTOBER 15, 2007
Room-Temperature Operation of Buffer-Free
GaSb–AlGaSb Quantum-Well Diode Lasers Grown
on a GaAs Platform Emitting at 1.65 m
M. Mehta, A. Jallipalli, J. Tatebayashi, Member, IEEE, M. N. Kutty, A. Albrecht, G. Balakrishnan, Member, IEEE,
L. R. Dawson, and D. L. Huffaker, Senior Member, IEEE
Abstract—Buffer-free growth of GaSb on GaAs using interfacial
misfit (IMF) layers may significantly improve the performance of
antimonide-based emitters operating between 1.6 and 3 m by in-
tegrating III–As and III–Sb materials. Using the IMF, we are able
to demonstrate a GaSb–AlGaSb quantum-well laser grown on a
GaAs substrate and emitting at 1.65 m, the longest known oper-
ating wavelength for this type of device. The device operates in the
pulsed mode at room temperature and shows 15-mW peak power
at 10 C and shows high characteristic temperature ( ) for an
Sb-based active region. Further improvements to IMF formation
can lead to high-performance lasers operating up to 3 m.
Index Terms—GaAs, GaSb, interfacial misfits (IMFs), semicon-
ductor lasers.
I. INTRODUCTION
A
NTIMONIDE (Sb)-based semiconductor lasers are an
attractive solution for several applications that require
emitters operating beyond standard fiber-based communication
wavelengths (1.55 m) such as carbon dioxide and phos-
phine detection, excitation of biological molecules for medical
sensing, free-space optical communication, and military scene
projection. In the last several decades, many researchers have
reported Sb-based lasers operating at the near-infrared (NIR)
( 2 m) or midwavelength IR (MWIR) range (between 2
and 5 m) [1]–[11]. Furthermore, high-performance lasers
exhibiting very low threshold current density, high modal gain,
high characteristics temperature ( ), and high output power
have been recently demonstrated [7]–[11]. These characteristics
of GaSb-based lasers emitting in the NIR range have made their
performance comparable to those of conventional InP-based
lasers. Commercialization of these Sb-based devices would be
enhanced by developing the devices on an established material
platform such as GaAs (or InP) substrates.
Interfacial misfit (IMF) arrays offer a method to grow
Sb-based layers on a GaAs platform without having to use
metamorphic buffer layers to relieve the 8% lattice mismatch
between GaAs and GaSb. Since IMF-based growth was first re-
ported, the technology has led to the demonstration of optically
Manuscript received February 23, 2007; revised June 29, 2007. This work was
supported in part by the U.S. Department of Commerce under Grant BS123456.
The authors are with the Center for High Technology Materials (CHTM),
University of New Mexico (UNM), Albuquerque, NM 87106 USA (e-mail:
huffaker@chtm.unm.edu).
Digital Object Identifier 10.1109/LPT.2007.904928
pumped GaSb–AlGaSb edge emitters and VCSELs grown
on Si substrates and an electrically injected GaSb–AlGaSb
vertical-cavity light-emitting diode monolithically embedded
between GaAs–AlGaAs distributed Bragg reflectors [12]–[14].
Work has also been conducted on the atomic modeling and
the material characterization of the IMF interface [15]. In this
letter, we report the demonstration of room-temperature oper-
ation of an electrically injected GaSb–AlGaSb quantum-well
(QW) laser grown on a GaAs substrate using IMF arrays at
the GaAs–GaSb interface. By monolithically integrating a
thermally conductive GaAs substrate with an Sb-based active
region, we demonstrate, to the best of our knowledge, the
longest wavelength QW laser grown on a GaAs substrate. This
report presents the foundation for a hybrid As–Sb approach to
devices operating between 1.6 and 3 m that might vastly im-
prove heat spreading and contact resistance in Sb-based lasers.
Improvements in each of these areas will also enable future
development of hybrid As-Sb VCSELs, avalanche photodiodes,
and photonic integrated circuits.
II. DEVICE DESIGN,GROWTH, AND FABRICATION
The growth of the laser structure is performed on a V80-H
solid-state molecular beam epitaxy reactor. The reactor houses
valved Sb and As crackers for precise control of Group V in-
corporation during growth. The reactor is also equipped with
a RHEED gun, critical to the confirmation of IMF formation
during growth. The growth is initiated with a 100-nm GaAs
smoothing layer followed by the IMF formation and 5 nm of
undoped GaSb growth. After deposition of the undoped GaSb
layer, growth proceeds directly to the doped AlGaSb n-type
cladding layer. The remainder of the growth is carried out using
conventional growth techniques for Sb-based devices.
The IMF is formed at the GaAs–GaSb interface through
two-dimensional packing of Sb atoms on the GaAs surface.
Misfit dislocations that form perpendicular to the plane of
growth relieve completely the strain due to the lattice mis-
match of the two materials. Moreover, we have confirmed
that these misfit dislocations arise in a periodic fashion at a
spacing corresponding directly with the lattice mismatch based
on high-resolution transmission electron micrograph (TEM)
analysis [16]. Previous modeling of the possible strain energies
confirms that the formation of an IMF is an energetically
favorable scenario during lattice mismatch growth [15].
A schematic of the complete device structure is illustrated
in Fig. 1. The p-type and n-type cladding layers are both
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