Research Article Exact Solution for Non-Self-Similar Wave-Interaction Problem during Two-Phase Four-Component Flow in Porous Media S. Borazjani, 1 P. Bedrikovetsky, 1 and R. Farajzadeh 2,3 1 Australian School of Petroleum, he University of Adelaide, SA 5005, Australia 2 Shell Global Solutions International, Rijswijk, he Netherlands 3 Delt University of Technology, he Netherlands Correspondence should be addressed to S. Borazjani; sara.borazjani@adelaide.edu.au Received 6 September 2013; Revised 27 December 2013; Accepted 29 December 2013; Published 12 March 2014 Academic Editor: Shuyu Sun Copyright © 2014 S. Borazjani et al. his is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Analytical solutions for one-dimensional two-phase multicomponent lows in porous media describe processes of enhanced oil recovery, environmental lows of waste disposal, and contaminant propagation in subterranean reservoirs and water management in aquifers. We derive the exact solution for 3×3 hyperbolic system of conservation laws that corresponds to two-phase four- component low in porous media where sorption of the third component depends on its own concentration in water and also on the fourth component concentration. Using the potential function as an independent variable instead of time allows splitting the initial system to 2×2 system for concentrations and one scalar hyperbolic equation for phase saturation, which allows for full integration of non-self-similar problem with wave interactions. 1. Introduction Exact self-similar solutions of Riemann problems for hyper- bolic systems of conservation laws and non-self-similar solutions of hyperbolic wave interactions have been derived for various lows in gas dynamics, shallow waters, and chromatography (see monographs [18]). For low in porous media, hyperbolic systems of conservation laws describe two- phase multicomponent displacement [9, 10]. Consider   + (,)  =0 (1) (+())  + ( (,))  =0, (2) where s is the saturation (volumetric fraction) of aqueous phase and f is the water lux. Equation (1) is the mass balance for water and (2) is the mass balance for each component in the aqueous solution. Under the conditions of thermodynamic equilibrium, the concentrations of the components adsorbed on the solid phase (a i ) and dissolved in the aqueous phase (c i ) are governed by adsorption isotherms: =(), =( 1 , 2 ,..., ), =( 1 , 2 ,..., ). (3) Exact and semianalytical solutions of one-dimensional low problems are widely used in stream-line simulation for low prediction in three-dimensional natural reservoirs [10]. he sequence of concentration shocks in the one-dimensional analytical solution is important for interpretation of labo- ratory tests in two-phase multicomponent low in natural reservoir cores. he scalar hyperbolic equations (1) and (2), =0, correspond to displacement of oil by water [9, 10]. he ( + 1) × ( + 1) system (1) and (2) describes two-phase low of oleic and aqueous phases with components (such as polymer and diferent salts) that may adsorb and be dissolved in both phases. hese lows are typical for so-called chemical enhanced oil recovery displacements, like injections of polymers or surfactants, and for numerous environmental lows [9, 10]. For polymer injection in oil reservoirs, =1 corresponds to polymer and =2,3,..., to diferent ions. Hindawi Publishing Corporation Abstract and Applied Analysis Volume 2014, Article ID 731567, 13 pages http://dx.doi.org/10.1155/2014/731567