World Journal of Condensed Matter Physics,2014, 4, 166-178
Published Online August 2014 in SciRes. http://www.scirp.org/journal/wjcmp
http://dx.doi.org/10.4236/wjcmp.2014.43021
How to cite this paper: Abdurakhmanov, G. (2014) On the Conduction Mechanism of Silicate Glass Doped by Oxide Com-
pounds of Ruthenium (Thick Film Resistors). 3. The Minimum of Temperature Dependence of Resistivity. World Journal of
Condensed Matter Physics, 4, 166-178. http://dx.doi.org/10.4236/wjcmp.2014.43021
On the Conduction Mechanism of Silicate
Glass Doped by Oxide Compounds of
Ruthenium (Thick Film Resistors).
3. The Minimum of Temperature
Dependence of Resistivity
Gulmurza Abdurakhmanov
The Institute of Power Engineering and Automation, The Uzbek Academy of Sciences, Tashkent,
Uzbekistan
Email: gulmirzo@mail.ru
Received 2 June 2014; revised 5 July 2014; accepted 21 July 2014
Copyright © 2014 by author and Scientific Research Publishing Inc.
This work is licensed under the Creative Commons Attribution International License (CC BY).
http://creativecommons.org/licenses/by/4.0/
Abstract
This article is the final part of the investigation of conduction mechanism of silicate glass doped by
oxide compounds of ruthenium (thick film resistors). In the first part [1], the formation of percola-
tion levels due to diffusion of dopant atoms into the glass has been considered. The diffusion me-
chanism allowed us to explain shifting of the percolation threshold towards to lower value and the
effect of firing conditions as well as the components composition on the electrical conduction of
the doped glass. The coexistence of thermal activation and localization of free charge carriers as
the result of nanocrystalline structure of the glass was the subject of the second part [2]. Because
of it, the resistivity of the doped silicate glass is proportional to exp (–aT
–ζ
) at low temperatures (T <
50 K), 0.4 < ζ < 0.8. Structural transitions of nanocrystals take place at high temperatures (T > 800
K) and the conductivity of the doped silicate glass decreases sharply. We consider the origin of the
minimum in the temperature dependence of resistivity of the doped silicate glass here. It is shown
that the minimum arises from merge of impurity band into the valence band of glass at tempera-
ture high enough, so thermal activation of charge carriers as well as its hopping are failed, and
scattering of free charge carriers become predominant factor in the temperature dependence of
the resistivity.
Keywords
Lead-Silicate Glass, Thick Film Resistors, Minimum of Resistivity, Doping, Energy Bands,
Conductivity, Thermal Activation, Hopping