292487)
RESEARCH ARTICLE
Copyright © 2015 American Scientific Publishers
All rights reserved
Printed in the United States of America
Journal of
Nanoelectronics and Optoelectronics
Vol. 10, 671–674, 2015
Effect of InAs/GaAs Quantum Dot Size on Infrared
Photoresponse Characteristics
Tien Dai Nguyen, Dong-Bum Seo, and Eui-Tae Kim
∗
Department of Materials Science and Engineering, Chungnam National University, Daejeon 305-764, Republic of Korea
Two types of InAs/GaAs quantum dots (QDs), namely, relatively large/steep QDs and small/shallow
QDs, are comprehensively studied for QD infrared photodetector (QDIP) applications. The QDIP
with small QDs shows a broad photoresponse over a relatively wide range (∼5 m to 7 m),
whereas its QDIP counterpart with large QDs yields a sharp photoresponse peak at ∼7.2 m with
a full width at half maximum of 32 meV. The systematic interband and intraband studies suggest
that the excited states involved in intraband transitions in QDIPs with small and large QDs have
continuum and QD-bound states, respectively. The QDIP with large QDs shows higher photocurrent-
to-dark current ratio than the QDIP with small QDs.
Keywords: Quantum Dot, InAs, Infrared, Detectors, QDIP.
1. INTRODUCTION
InAs/GaAs self-assembled quantum dots (QDs) have been
extensively studied for various applications, such as pho-
todetectors and lasers.
1–7
QD infrared (IR) photodetec-
tors (QDIPs) have several advantages over quantum-well
(QW) IR photodetectors (QWIPs). Three-dimensionally
confined QDs make QDIPs intrinsically sensitive to nor-
mally incident radiation,
1–7
unlike QWIPs.
8
Given the
phonon bottleneck effects,
9 10
QDs can also have longer
carrier relaxation time than QWs. Thus, QDIPs have
potentially lower dark current and relatively higher photo-
electric gain.
11
The performance of QDIPs is affected by various fac-
tors such as QDIP structure, carrier doping, and growth
conditions.
1–3
Among them, QD size and shape are the
most important factors determining the nature charac-
teristics of QD inter and intraband transitions for IR
detection.
12–15
To some extent the QD size can be var-
ied depending on desired detection bands of QDIPs. Cal-
culation and experimental results show that the ground
state interband transition energy and the energy level sep-
arations increase (blueshift) with decreasing QD size.
12–15
Moreover, the binding energies, with respect to the GaAs
conduction band edge, of carriers sitting in the ground
and final electronic states of intraband transitions are sig-
nificantly different depending on QD size and shape. In
this study, QDIPs having two types of QDs (relatively
large/steep QDs and small/shallow QDs) are compared to
∗
Author to whom correspondence should be addressed.
each other. The two QDIPs show the apparent difference of
QDIP performance such as IR photoresponse and dark cur-
rent. Moreover, these QDIP studies reveal QD electronic
structure and the nature of interband and intraband transi-
tions and QD electronic states involved such transitions.
2. EXPERIMENTAL DETAILS
QDIP samples were grown on semi-insulating GaAs
(001) substrates through the use of solid-source molecular
beam epitaxy (MBE) under As pressure of 7 × 10
6
Torr.
A schematic of the InAs/GaAs QDIP structures is shown
in Figure 1. The QDIP samples consisted of an undoped,
active InAs QD region sandwiched between highly Si-
doped GaAs contact layers. A Si-doped GaAs contact layer
[1 × 10
18
cm
3
(0.7 m)/1 × 10
17
cm
3
(0.3 m)] was grown
at a growth rate of 0.5 monolayer (ML)/sec at 600
C.
An undoped 220 ML-thick GaAs layer was then grown
at 0.25 ML/s at 600
C. The small and large QD lay-
ers were formed with the use of 2.0 and 3.0 ML InAs
deposition, respectively, at a growth rate of 0.22 ML/s
at 500
C. The 3.0 ML InAs deposition was performed
through punctuated island growth (PIG) approach with the
deposition sequence 2.0 ML InAs + 60 s punctuation +
1.0 ML InAs.
16
The InAs QDs were followed by GaAs
capping layer deposited under migration-enhanced epitaxy
mode up to 40 ML at 0.25 ML/s at 350
C, and then
by conventional MBE growth at 500
C. The total thick-
nesses of capping layers were 100 and 150 ML for 2.0 and
3.0 ML InAs QDs, respectively. The QD growth and cap-
ping procedure was repeated five times. Finally, a 0.5 m
J. Nanoelectron. Optoelectron. 2015, Vol. 10, No. 5 1555-130X/2015/10/671/004 doi:10.1166/jno.2015.1823 671