A. Wantuch, E. Kurgan, P. Gas, “Numerical Analysis on Cathodic Protection of Underground Structures”,
2016 13th Selected Issues of Electrical Engineering and Electronics (WZEE),
IEEE Xplore, 2016, art. no. 7800225, [pp. 1-4]. Available at: http://dx.doi.org/10.1109/WZEE.2016.7800225
978-1-5090-1015-8/16/$31.00 ©2016 IEEE
Numerical Analysis on Cathodic Protection of
Underground Structures
Agnieszka Wantuch
1)
, Eugeniusz Kurgan
2)
, Piotr Gas
3)
AGH University of Science and Technology
Department of Electrical and Power Engineering
al. Mickiewicza 30, 30-059 Krakow, Poland
e-mails:
1)
awantuch@agh.edu.pl,
2)
kurgan@agh.edu.pl,
3)
piotr.gas@agh.edu.pl
Abstract — The presented paper describes the principles
of cathodic protection (CP) of underground tanks using the
sacrificial anode as well as method of calculation of the potential,
current density and polarization distribution on all sides metallic
tanks buried underground. Differential equations with boundary
conditions are developed and next solved by FEM in 2D and 3D
cases. The main goal of this publication is the computation of
such distribution of the external protecting electrodes where
protected structure will not corrode and next the calculations in
2D and 3D were compared. The article shows that it is sufficient
to use 2D analysis for which the speed of equations solution is
significantly larger than in 3D space.
Keywords — impressed cathodic protection; corrosion; galvanic
protection; finite element method
I. INTRODUCTION
The term “corrode” is derived from the Latin word
“corrodere”, which means “to gnaw to pieces”. Corrosion is
a natural process and it can be defined in many ways,
for example as a destruction of metals by a chemical or
electrochemical interaction with environment that produces a
deterioration of the material and its properties. If the steel is
e.g. in a dump ground that contains chemicals, the rusting
process accelerates. Elements that influence on underground
corrosion could be: soil pH value, soil resistivity, wetness,
aeration, and other corrosive agents [1]. Corrosion in aqueous
solutions proceeds by an electro-chemical process, therefore
anodic and cathodic electro-chemical reactions must occur
simultaneously. Any metal structures buried in the ground,
such as pipelines, tanks are vulnerable to damage caused by
the operation located in corrosive soil.
From many years the problem of protection against
corrosion has been described in many publications. Review of
numerical methods applied for corrosion protection issue can
be found at [2], [3], [4]. Simulation by adequate partial
differential equations by finite element is the major technique
used in a analysis of such problems. To accomplish the
simulation of the different structures, it is required to have
adequate data to serve as boundary condition at the different
surface locations of the structure. On corroding surface
different electrochemical reactions take place. From numerical
simulation point of view, they can be represented by Butler-
Volmer equation, which relates current density on surface
from overpotential. This relation is highly nonlinear and has to
be fulfilled on both anodes and cathodes. This fact causes
substantial numerical difficulties by solution adequate partial
differential equations with such highly nonlinear boundary
conditions.
Corrosion is a problem in many areas of life. It appears
both in industry, construction, as well as household [5]. The
damage caused by corrosion into the millions per year.
Corrosion is still a huge problem so continued research is
carried out to stop it.
II. THE PRINCIPLES OF CATHODIC PROTECTION
Metallic piping and propane tanks need cathodic protection
to live a long time. Plating, painting or covering the steel tanks
by the polyurethane coatings in the factory is the first line of
protection against corrosion. But a coating system doesn’t give
100 % efficiency, only 50 to 99 % depending method of
installation, upon age. Cathodic protection can be considered
as the second line of defense. Importantly, it is one of the most
common used electrical methods of corrosion prevention on
metallic objects which are in water or soil [6] or there are
exposed to other aggressive environment [7].
A. Theoretical Background
In the process of corrosion two types of electrochemical
reactions, anodic and cathodic, can be identified [8]. The most
important cathodic reactions are the evolution of H
2
from acid,
neutral or alkaline solution:
2 2
2H O 2e H 2OH
2
2H 2e H
Corrosion always occurs in the anode. The anodic reaction
takes place:
2
Fe 2e Fe
The free electrons, which pass to another site on the metal
surface, are absorbed by the cathodic reaction. The difference
in natural potentials between the steel and the anode causes
a positive current to flow from the anode to the steel, which
becomes the cathode, because in this case, the total surface of
the metal object becomes more negatively charged.